Publicação
Cyclic Voltammetry of Ruthenium Complexes for Nonlinear Optics
| Resumo: | We report herein the cyclic voltammetry studies of the compounds [RuCp(P_P)(NC{SC4H2}nNO2)][PF6] (P_P=DPPE, (+)-DIOP; n=1-3) in dichloromethane and acetonitrile. The electronic richness of the organometallic moiety together with the evaluation of the corresponding HOMO-LUMO gaps and correlation with spectroscopic data will be addressed. The overall data will be used in order to give an insight on the SONLO properties of these compounds. |
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| Autores principais: | Mendes, Paulo J. G. |
| Assunto: | Ruthenium complexes cyclic voltammetry nonlinear optics |
| Ano: | 2008 |
| País: | Portugal |
| Tipo de documento: | palestra |
| Tipo de acesso: | acesso restrito |
| Instituição associada: | Universidade de Évora |
| Idioma: | inglês |
| Origem: | Repositório Científico da Universidade de Évora |
| Resumo: | We report herein the cyclic voltammetry studies of the compounds [RuCp(P_P)(NC{SC4H2}nNO2)][PF6] (P_P=DPPE, (+)-DIOP; n=1-3) in dichloromethane and acetonitrile. The electronic richness of the organometallic moiety together with the evaluation of the corresponding HOMO-LUMO gaps and correlation with spectroscopic data will be addressed. The overall data will be used in order to give an insight on the SONLO properties of these compounds. |
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