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Mind the Microgap in Iridescent Cellulose Nanocrystal Films

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Detalhes bibliográficos
Resumo:Researchers reported a new cellulose-based photonic structure, which reflected both right circularly polarized (RCP) and left circularly polarized (LCP) light that can be tuned by temperature variation and the application of an external electric field. The optical properties of the cellulose nanocrystal (CNC) samples were investigated both in terms of their microstructure by scanning electron microscopy (SEM), small-angle X-ray scattering (SAXS) and spectroscopically, using circularly and linear polarized light coupled with a polarized optical microscope (POM). The nanocrystals used in this work were prepared by acid hydrolysis of microcrystalline cellulose. Aqueous suspensions of CNCs in the acid form were used, resulting in freestanding iridescent films after drying with colors depending on the viewing angle.
Autores principais:Fernandes, Susete N.
Outros Autores:Almeida, Pedro L.; Monge, Nuno; Aguirre, Luis E.; Reis, Dennys; de Oliveira, Cristiano L. P.; Neto, António M. F.; Pieranski, Pawel; Godinho, Maria Helena
Assunto:cellulose nanocrystals liquid crystals mimicking Plusiotis resplendens cuticles photonics General Materials Science Mechanics of Materials Mechanical Engineering
Ano:2017
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Universidade Nova de Lisboa
Idioma:inglês
Origem:Repositório Institucional da UNL
Descrição
Resumo:Researchers reported a new cellulose-based photonic structure, which reflected both right circularly polarized (RCP) and left circularly polarized (LCP) light that can be tuned by temperature variation and the application of an external electric field. The optical properties of the cellulose nanocrystal (CNC) samples were investigated both in terms of their microstructure by scanning electron microscopy (SEM), small-angle X-ray scattering (SAXS) and spectroscopically, using circularly and linear polarized light coupled with a polarized optical microscope (POM). The nanocrystals used in this work were prepared by acid hydrolysis of microcrystalline cellulose. Aqueous suspensions of CNCs in the acid form were used, resulting in freestanding iridescent films after drying with colors depending on the viewing angle.

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