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2,2'-(2,2'-oxybis(ethane-2,1-diyl)bis(oxy))bis(N-(2,2'-bithiophen-5-ylmethylene)aniline)

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Detalhes bibliográficos
Resumo:A new flexible fluorescent compound L derived from 1,5-bis(2-aminophenoxy)-3-oxapentane (A) has been synthesized by classical Schiff-base reaction between (A) and 2,2 ́-bithiophene carbaldehyde (B). The same synthesis was reproduced by a green methodology using an ultrasonication reaction in a classical sonication bath. The structure of the new compound was confirmed by elemental analysis, IR, 1H-NMR, MALDI-TOF-MS and EI-MS-spectra, UV-vis and fluorescence emission spectroscopy.
Autores principais:Pedras, Bruno
Outros Autores:Gallego, Daniel; Figueiredo, Patrick L.; Nunes-Miranda, Júlio Dinis; Capelo, José Luis; Lodeiro, Carlos
Assunto:2,2'-bithiophene Fluorescence chemosensors Imine compounds Biochemistry Physical and Theoretical Chemistry Organic Chemistry
Ano:2010
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Universidade Nova de Lisboa
Idioma:inglês
Origem:Repositório Institucional da UNL
Descrição
Resumo:A new flexible fluorescent compound L derived from 1,5-bis(2-aminophenoxy)-3-oxapentane (A) has been synthesized by classical Schiff-base reaction between (A) and 2,2 ́-bithiophene carbaldehyde (B). The same synthesis was reproduced by a green methodology using an ultrasonication reaction in a classical sonication bath. The structure of the new compound was confirmed by elemental analysis, IR, 1H-NMR, MALDI-TOF-MS and EI-MS-spectra, UV-vis and fluorescence emission spectroscopy.

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