Detalhes bibliográficos
| Resumo: | Electron-acceptor units, combined with bithiophene substituted with flexible chains end-functionalized with cross-linkable moieties, provide soluble donor-acceptor-donor (DAD) it-conjugated oligomer-type molecules with cross-linking ability and broad absorption in the visible spectrum. A study on the cross-linking conditions of the new oligomers to yield insoluble polymer networks is presented, including conditions for obtaining polymer films over poly(3,4-ethylenedioxythiophene):polystyrene sulfonate-covered substrates. The combination of the DAD molecular design and cross-linking functionality opens prospects for applications in solution-processed small-molecule solar cells with morphologically-stable organic layers. |
| Autores principais: | Brotas, Graça |
| Outros Autores: | Costa, Cristiana; Dias, Sandra I. G.; Costa, Pedro M. M.; Paolo, Roberto E. Di; Martins, João; personFarinhas, Joana; Alcácer, Luís; personJorge Morgado; personMatos, Manuel; personCharas, Ana |
| Assunto: | conjugated oligomers cross-linking macromonomers organic photovoltaics cross-structure-property relations |
| Ano: | 2015 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso restrito |
| Instituição associada: | Universidade Politécnica de Lisboa |
| Idioma: | inglês |
| Origem: | Repositório Científico da Universidade Politécnica de Lisboa |