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Chitosan and gum arabic nanoparticles for heavy metal adsorption

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Detalhes bibliográficos
Resumo:Abstract Chitosan (CT) is a polysaccharide with the ability to adsorb metals on its surface. In this work, CT-based nanoparticles (NPs) are produced by complex formation with gum arabic (GA) to increase their adsorbent potential for removal of heavy metals in aqueous medium. Adsorption efficiency is evaluated as a function of NP composition and polysaccharide concentration. NPs are sized from 250 to 375 nm at a zeta potential up to -25 mV, suggesting stability to adsorb metals. In particular, CTGA56 and CTGA80 NPs adsorbed a substantially higher amount of copper ions than pure CT. Adsorption kinetics studies showed that the reaction process followed a pseudo second-order model and the adsorption isotherm results fit a Langmuir model, highlighting the monolayer adsorption process with prominent adsorption capacity. These findings indicate the adsorbent potential of CTGA NPs and suggest that these particles can be used for removal of metal ions from contaminated water sources.
Autores principais:Abreu,Flavia Oliveira Monteiro da Silva
Outros Autores:Silva,Nilvan Alves da; Sipauba,Mateus de Sousa; Pires,Tamara Fernandes Marques; Bomfim,Tatiana Araújo; Monteiro Junior,Oyrton Azevedo de Castro; Forte,Maria Madalena de Camargo
Assunto:adsorption chitosan nanoparticles polyelectrolytes
Ano:2018
País:Brasil
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:IBICT
Idioma:inglês
Origem:Oasisbr
Descrição
Resumo:Abstract Chitosan (CT) is a polysaccharide with the ability to adsorb metals on its surface. In this work, CT-based nanoparticles (NPs) are produced by complex formation with gum arabic (GA) to increase their adsorbent potential for removal of heavy metals in aqueous medium. Adsorption efficiency is evaluated as a function of NP composition and polysaccharide concentration. NPs are sized from 250 to 375 nm at a zeta potential up to -25 mV, suggesting stability to adsorb metals. In particular, CTGA56 and CTGA80 NPs adsorbed a substantially higher amount of copper ions than pure CT. Adsorption kinetics studies showed that the reaction process followed a pseudo second-order model and the adsorption isotherm results fit a Langmuir model, highlighting the monolayer adsorption process with prominent adsorption capacity. These findings indicate the adsorbent potential of CTGA NPs and suggest that these particles can be used for removal of metal ions from contaminated water sources.

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