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Chiral Lewis acid catalysts in diels-Alder cycloadditions: mechanistic aspects and synthetic applications of recent systems

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Detalhes bibliográficos
Resumo:This review summarizes the recent progress which has been made in the use of chiral Lewis Acid catalysts in Diels-Alder cycloaddition reactions. Chiral catalysts containing aluminum, boron, titanium, copper, lanthanides, magnesium and transition-metals are critically reviewed. Structural studies on Lewis acid carbonyl complexes and synthetic applications of recent systems are specifically discussed.
Autores principais:Dias,Luiz C
Assunto:asymmetric Diels-Alder cycloaddition reaction chiral Lewis acids asymmetric catalysis dienophile-Lewis acid complex
Ano:1997
País:Brasil
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:IBICT
Idioma:inglês
Origem:Oasisbr
Descrição
Resumo:This review summarizes the recent progress which has been made in the use of chiral Lewis Acid catalysts in Diels-Alder cycloaddition reactions. Chiral catalysts containing aluminum, boron, titanium, copper, lanthanides, magnesium and transition-metals are critically reviewed. Structural studies on Lewis acid carbonyl complexes and synthetic applications of recent systems are specifically discussed.

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