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Adsorption of turquoise blue QG reactive bye commercial activated carbon in batch reactor: kinetic and equilibrium studies

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Summary:The adsorption of reactive turquoise blue QG dye on commercial activated carbon was investigated in a batch reactor to obtain isotherm and kinetic data under different experimental conditions. The adsorbent was characterized by a FTIR method to analyze surface area and pH PZC and to identify functional groups. Experiments were conducted to obtain equilibrium data at 30°C, with the pH effect being assayed in the range of 2 to 8. Experiments were then carried out under the optimal pH condition for dye removal to obtain equilibrium data at 30°C, 45°C and 60°C. Adsorption isotherm models were used to correlate the equilibrium data. Maximum dye removal capacity was observed at a pH of 2 and temperature of 30°C. The kinetic experiments were carried out at a pH of 2 and at three different temperatures: 30°C, 45°C and 60°C. Pseudo-second-order models were used to describe the kinetics of dye adsorption.
Main Authors:Schimmel,D.
Other Authors:Fagnani,K. C.; Santos,J. B. Oliveira dos; Barros,M. A. S. D.; Silva,E. Antonio da
Subject:Reactive dye Activated carbon Adsorption Isotherm Kinetics Enthalpy of adsorption
Year:2010
Country:Brazil
Document type:article
Access type:open access
Associated institution:IBICT
Language:English
Origin:Oasisbr
Description
Summary:The adsorption of reactive turquoise blue QG dye on commercial activated carbon was investigated in a batch reactor to obtain isotherm and kinetic data under different experimental conditions. The adsorbent was characterized by a FTIR method to analyze surface area and pH PZC and to identify functional groups. Experiments were conducted to obtain equilibrium data at 30°C, with the pH effect being assayed in the range of 2 to 8. Experiments were then carried out under the optimal pH condition for dye removal to obtain equilibrium data at 30°C, 45°C and 60°C. Adsorption isotherm models were used to correlate the equilibrium data. Maximum dye removal capacity was observed at a pH of 2 and temperature of 30°C. The kinetic experiments were carried out at a pH of 2 and at three different temperatures: 30°C, 45°C and 60°C. Pseudo-second-order models were used to describe the kinetics of dye adsorption.

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