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Intercalação Eletroquímica de Cátions Hexilamínio na Matriz Lamelar 1T-TiS2

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Resumo:The electrochemical synthesis of a ternary compound obtained by the intercalation of hydrated hexilaminium cations into the layered compound 1T-TiS2 is reported. Two different compounds were detected by cyclovoltammetry and studied by X-ray diffractometry. Models showing the steric arrangement of the hydrated hexilaminium cations into the Van der Waals gaps were proposed.
Autores principais:Wypych,Fernando
Outros Autores:Gomes,Maria A. B.; Adad,Luciana B.; Denicoló,Ireno
Assunto:intercalation compounds electrochemistry titanium disulfide
Ano:1997
País:Brasil
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:IBICT
Idioma:português
Origem:Oasisbr
Descrição
Resumo:The electrochemical synthesis of a ternary compound obtained by the intercalation of hydrated hexilaminium cations into the layered compound 1T-TiS2 is reported. Two different compounds were detected by cyclovoltammetry and studied by X-ray diffractometry. Models showing the steric arrangement of the hydrated hexilaminium cations into the Van der Waals gaps were proposed.

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