Publicação
Kinetic Modeling of Non-Linear Polymerization
| Resumo: | Recent developments of a method based upon population balances of generating functions of polymer chain length distributions (CLD) are presented. The calculation of the CLD and how to take into account chain length dependent reactivity are discussed. Prediction of polymer properties is also possible but only easily done for the average molecular radius of gyration; some results are presented for a radical polymerization including transfer to polymer and propagation with terminal double bonds. |
|---|---|
| Autores principais: | Costa, Mário Rui |
| Outros Autores: | Dias, Rolando |
| Assunto: | Gelation Molecular weight distribution Non-linear polymers Radical polymerization Ziegler-Natta polymerization |
| Ano: | 2006 |
| País: | Portugal |
| Tipo de documento: | comunicação em conferência |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade Politécnica de Bragança |
| Idioma: | inglês |
| Origem: | Biblioteca Digital da UPB |
| Resumo: | Recent developments of a method based upon population balances of generating functions of polymer chain length distributions (CLD) are presented. The calculation of the CLD and how to take into account chain length dependent reactivity are discussed. Prediction of polymer properties is also possible but only easily done for the average molecular radius of gyration; some results are presented for a radical polymerization including transfer to polymer and propagation with terminal double bonds. |
|---|