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Scanning probe microscopic imaging of guanine on a highly oriented pyrolytic graphite electrode

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Detalhes bibliográficos
Resumo:Guanine adsorbed onto a highly oriented pyrolytic graphite electrode was studied by MAC-Mode Atomic Force Microscopy (AFM), and the electrochemical behaviour of the guanine layer was investigated with Electrochemical AFM. Guanine adsorbs spontaneously, without forming a well-packed structure, into nucleation spots, which are stable with time and cover the surface uniformly and almost completely. The process of guanine adsorption and nucleation can be controlled and the effect of altering the exposure time and varying the potential was investigated.
Autores principais:Paquim, A. M. Chiorcea
Outros Autores:Brett, A. M. Oliveira
Assunto:Guanine Adsorbtion Pyrolytic graphite Atomic force microscopy
Ano:2002
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso aberto
Instituição associada:Universidade de Coimbra
Idioma:inglês
Origem:Estudo Geral - Universidade de Coimbra
Descrição
Resumo:Guanine adsorbed onto a highly oriented pyrolytic graphite electrode was studied by MAC-Mode Atomic Force Microscopy (AFM), and the electrochemical behaviour of the guanine layer was investigated with Electrochemical AFM. Guanine adsorbs spontaneously, without forming a well-packed structure, into nucleation spots, which are stable with time and cover the surface uniformly and almost completely. The process of guanine adsorption and nucleation can be controlled and the effect of altering the exposure time and varying the potential was investigated.

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