Publication
Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters
| Summary: | Two sequential injection methodologies for the spectrophotometric determination of reactive aluminium in water samples are proposed, based on the reaction between chrome azurol S (CAS) and aluminium. The two methods involve a direct and a kinetic methodology (for its application to coloured waste waters), both accommodated within the same manifold. The working ranges obtained were: 0.040-0.500 mg Al Lˉ¹ for direct method and 0.050-0.300 mg Al Lˉ¹ for the kinetic method. The described system has high degree of automation, enabling sampling throughputs of 31 and 57 hˉ¹ for the kinetic method and direct methods, respectively. The reagents consumption per determination is low: 46 μg of CAS, 3.75 mg of sodium acetate and 25 μg of ascorbic acid. The volume of effluent produced per determination is only around 2.8 mL in the direct method and 3.4 mL in the kinetic method. |
|---|---|
| Main Authors: | Mesquita, Raquel B. R. |
| Other Authors: | Rangel, António O. S. S. |
| Subject: | Sequential injection Spectrophotometry Aluminium Waters kinetic determination |
| Year: | 2008 |
| Country: | Portugal |
| Document type: | article |
| Access type: | open access |
| Associated institution: | Universidade Católica Portuguesa |
| Language: | English |
| Origin: | Veritati - Repositório Institucional da Universidade Católica Portuguesa |
| _version_ | 1877783588223582208 |
|---|---|
| author | Mesquita, Raquel B. R. |
| author2 | Rangel, António O. S. S. |
| author2_role | author |
| author_facet | Mesquita, Raquel B. R. Rangel, António O. S. S. |
| author_role | author |
| contributor_name_str_mv | Veritati |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Mesquita, Raquel B. R.\",\"Person.identifier.cienciaID\":\"EB1D-DEE3-0B60\",\"Person.identifier.orcid\":\"0000-0001-7745-1860\",\"Person.identifier.researcherID\":\"J-4630-2013\",\"Person.identifier.scopusAuthorID\":\"7005556626\",\"Person.identifier.scopusAuthorID\":\"7005556626\"},{\"Person.name\":\"Rangel, António O. S. S.\",\"Person.identifier.cienciaID\":\"D61D-7CFB-178A\",\"Person.identifier.orcid\":\"0000-0002-6486-8947\",\"Person.identifier.scopusAuthorID\":\"7004827387\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | Veritati |
| datacite.creators.creator.creatorName.fl_str_mv | Mesquita, Raquel B. R. Rangel, António O. S. S. |
| datacite.date.Accepted.fl_str_mv | 2008-01-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2010-10-11T10:52:40Z |
| datacite.date.embargoed.fl_str_mv | 2010-10-11T10:52:40Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | Sequential injection Spectrophotometry Aluminium Waters kinetic determination |
| datacite.titles.title.fl_str_mv | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| dc.contributor.none.fl_str_mv | Veritati |
| dc.creator.none.fl_str_mv | Mesquita, Raquel B. R. Rangel, António O. S. S. |
| dc.date.Accepted.fl_str_mv | 2008-01-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2010-10-11T10:52:40Z |
| dc.date.embargoed.fl_str_mv | 2010-10-11T10:52:40Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10400.14/2772 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | Sociedade Brasileira de Química |
| dc.rights.cclincense.fl_str_mv | http://creativecommons.org/licenses/by-nc/4.0/ |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | Sequential injection Spectrophotometry Aluminium Waters kinetic determination |
| dc.title.fl_str_mv | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Two sequential injection methodologies for the spectrophotometric determination of reactive aluminium in water samples are proposed, based on the reaction between chrome azurol S (CAS) and aluminium. The two methods involve a direct and a kinetic methodology (for its application to coloured waste waters), both accommodated within the same manifold. The working ranges obtained were: 0.040-0.500 mg Al Lˉ¹ for direct method and 0.050-0.300 mg Al Lˉ¹ for the kinetic method. The described system has high degree of automation, enabling sampling throughputs of 31 and 57 hˉ¹ for the kinetic method and direct methods, respectively. The reagents consumption per determination is low: 46 μg of CAS, 3.75 mg of sodium acetate and 25 μg of ascorbic acid. The volume of effluent produced per determination is only around 2.8 mL in the direct method and 3.4 mL in the kinetic method. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://repositorio.ucp.pt/bitstreams/b45960ea-6818-4a8a-a487-cdf1588cbbfe/download |
| id | veritati_0633ccdaaf053318b1c23c36bcbf4dde |
| identifier.url.fl_str_mv | http://hdl.handle.net/10400.14/2772 |
| inst_facet_str | urn:organizationAcronym:ucp{{{_:::_}}}Universidade Católica Portuguesa |
| instacron_str | ucp |
| institution | Universidade Católica Portuguesa |
| instname_str | Universidade Católica Portuguesa |
| language | eng |
| network_acronym_str | veritati |
| network_name_str | Veritati - Repositório Institucional da Universidade Católica Portuguesa |
| oai_identifier_str | oai:repositorio.ucp.pt:10400.14/2772 |
| organization_str_mv | urn:organizationAcronym:ucp |
| person_str_mv | Mesquita, Raquel B. R. Mesquita, Raquel B. R. https://www.ciencia-id.pt/EB1D-DEE3-0B60 EB1D-DEE3-0B60 http://orcid.org/0000-0001-7745-1860 0000-0001-7745-1860 Rangel, António O. S. S. Rangel, António O. S. S. https://www.ciencia-id.pt/D61D-7CFB-178A D61D-7CFB-178A http://orcid.org/0000-0002-6486-8947 0000-0002-6486-8947 |
| publishDate | 2008 |
| publisher.none.fl_str_mv | Sociedade Brasileira de Química |
| repo_facet_str | urn:repositoryAcronym:veritati{{{_:::_}}}Veritati - Repositório Institucional da Universidade Católica Portuguesa |
| reponame_str | Veritati - Repositório Institucional da Universidade Católica Portuguesa |
| repository_id_str | urn:repositoryAcronym:veritati |
| service_str_mv | urn:repositoryAcronym:veritati |
| spelling | engSociedade Brasileira de QuímicaporTwo sequential injection methodologies for the spectrophotometric determination of reactive aluminium in water samples are proposed, based on the reaction between chrome azurol S (CAS) and aluminium. The two methods involve a direct and a kinetic methodology (for its application to coloured waste waters), both accommodated within the same manifold. The working ranges obtained were: 0.040-0.500 mg Al Lˉ¹ for direct method and 0.050-0.300 mg Al Lˉ¹ for the kinetic method. The described system has high degree of automation, enabling sampling throughputs of 31 and 57 hˉ¹ for the kinetic method and direct methods, respectively. The reagents consumption per determination is low: 46 μg of CAS, 3.75 mg of sodium acetate and 25 μg of ascorbic acid. The volume of effluent produced per determination is only around 2.8 mL in the direct method and 3.4 mL in the kinetic method.application/pdfporDevelopment of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste watersPersonalMesquita, Raquel B. R.DSpacehttp://dspace.org/items/f89887f1-4d1b-438b-8f03-27d9bda1de7bDSpacehttp://dspace.org/items/f89887f1-4d1b-438b-8f03-27d9bda1de7bMesquitaRaquelCiência IDhttps://www.ciencia-id.ptEB1D-DEE3-0B60ORCIDhttp://orcid.org0000-0001-7745-1860Researcher IDhttps://www.researcherid.comJ-4630-2013Scopus Author IDhttps://www.scopus.com7005556626Scopus Author IDhttps://www.scopus.com7005556626PersonalRangel, António O. S. S.DSpacehttp://dspace.org/items/467be022-fd9c-4549-aa48-48ebcc1098ebDSpacehttp://dspace.org/items/467be022-fd9c-4549-aa48-48ebcc1098ebSantos Silva RangelAntónio OsmaroCiência IDhttps://www.ciencia-id.ptD61D-7CFB-178AORCIDhttp://orcid.org0000-0002-6486-8947Scopus Author IDhttps://www.scopus.com7004827387HostingInstitutionOrganizationalVeritatie-mailmailto:repositorio@ucp.ptrepositorio@ucp.ptDOIIsPartOf10.1590/S0103-505320080006000182010-10-11T10:52:40Z20082008-01-01T00:00:00ZHandlehttp://hdl.handle.net/10400.14/2772http://purl.org/coar/access_right/c_abf2open accessSequential injectionSpectrophotometryAluminiumWaterskinetic determination237476 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal article2008http://creativecommons.org/licenses/by-nc/4.0/http://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://repositorio.ucp.pt/bitstreams/b45960ea-6818-4a8a-a487-cdf1588cbbfe/download |
| spellingShingle | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters Mesquita, Raquel B. R. Sequential injection Spectrophotometry Aluminium Waters kinetic determination |
| status | SINGLETON |
| subject.fl_str_mv | Sequential injection Spectrophotometry Aluminium Waters kinetic determination |
| title | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| title_full | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| title_fullStr | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| title_full_unstemmed | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| title_short | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| title_sort | Development of sequential injection methodologies for the spectrophotometric direct and kinetic determination of aluminium in natural and waste waters |
| topic | Sequential injection Spectrophotometry Aluminium Waters kinetic determination |
| topic_facet | Sequential injection Spectrophotometry Aluminium Waters kinetic determination |
| url | http://hdl.handle.net/10400.14/2772 |
| visible | 1 |
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