Publication
Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode
| Summary: | Abstract In this study, gold nanoparticles (AuNPs) were synthesized using sodium borohydride (NaBH4) as reductant. AuNPs size and shape were experimented by using various characterization techniques. The synthesized AuNPs performance capability for atrazine (ATR) detection, at a glassy carbon electrode (GCE), was verified using cyclic voltammetry (CV) as the determining mode. AuNPs impressive electrochemical performance and stability at the GCE led to further studies, without the need to apply nafion. ATR linear concentration plot ranged from 10 to 17 nM, with a lower limit of detection (LOD) of 0.17 nM, and a regression coefficient (R2) of 0.9934, under optimized conditions. The proposed sensor was very reliable, with a relative standard deviation (RSD) of 1.1%, for n = 20, and it was quite sensitive for ATR, with no discernible interference from other ions. Consequently, AuNPs were effectively used to identify ATR in several pesticide industry wastewater samples. |
|---|---|
| Main Authors: | Memon,Safia Sanam |
| Other Authors: | Waris,Muhammad; Sidhu,Ahmed Raza; Zaqa,Marriam |
| Subject: | ATR AuNPs GCE, sensor wastewater |
| Year: | 2022 |
| Country: | Portugal |
| Document type: | article |
| Access type: | open access |
| Associated institution: | Fundação para a Ciência e Tecnologia |
| Language: | English |
| Origin: | SciELO Portugal |
| _version_ | 1877792035640967168 |
|---|---|
| author | Memon,Safia Sanam |
| author2 | Waris,Muhammad Sidhu,Ahmed Raza Zaqa,Marriam |
| author2_role | author author author |
| author_facet | Memon,Safia Sanam Waris,Muhammad Sidhu,Ahmed Raza Zaqa,Marriam |
| author_role | author |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Memon,Safia Sanam\"},{\"Person.name\":\"Waris,Muhammad\"},{\"Person.name\":\"Sidhu,Ahmed Raza\"},{\"Person.name\":\"Zaqa,Marriam\"}] |
| datacite.creators.creator.creatorName.fl_str_mv | Memon,Safia Sanam Waris,Muhammad Sidhu,Ahmed Raza Zaqa,Marriam |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | ATR AuNPs GCE, sensor wastewater |
| datacite.titles.title.fl_str_mv | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| dc.creator.none.fl_str_mv | Memon,Safia Sanam Waris,Muhammad Sidhu,Ahmed Raza Zaqa,Marriam |
| dc.format.none.fl_str_mv | text/html |
| dc.identifier.none.fl_str_mv | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042022000500363 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | Sociedade Portuguesa de Electroquímica |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.source.none.fl_str_mv | Portugaliae Electrochimica Acta v.40 n.5 2022 |
| dc.subject.none.fl_str_mv | ATR AuNPs GCE, sensor wastewater |
| dc.title.fl_str_mv | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Abstract In this study, gold nanoparticles (AuNPs) were synthesized using sodium borohydride (NaBH4) as reductant. AuNPs size and shape were experimented by using various characterization techniques. The synthesized AuNPs performance capability for atrazine (ATR) detection, at a glassy carbon electrode (GCE), was verified using cyclic voltammetry (CV) as the determining mode. AuNPs impressive electrochemical performance and stability at the GCE led to further studies, without the need to apply nafion. ATR linear concentration plot ranged from 10 to 17 nM, with a lower limit of detection (LOD) of 0.17 nM, and a regression coefficient (R2) of 0.9934, under optimized conditions. The proposed sensor was very reliable, with a relative standard deviation (RSD) of 1.1%, for n = 20, and it was quite sensitive for ATR, with no discernible interference from other ions. Consequently, AuNPs were effectively used to identify ATR in several pesticide industry wastewater samples. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| id | scielopt_dff9ef23b3da6b0611bfa1de849064f7 |
| identifier.url.fl_str_mv | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042022000500363 |
| inst_facet_str | urn:organizationAcronym:scielo{{{_:::_}}}Fundação para a Ciência e Tecnologia |
| instacron_str | SciELO |
| institution | Fundação para a Ciência e Tecnologia |
| instname_str | Fundação para a Ciência e Tecnologia |
| language | eng |
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| network_name_str | SciELO Portugal |
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| organization_str_mv | urn:organizationAcronym:scielo |
| person_str_mv | Memon,Safia Sanam Waris,Muhammad Sidhu,Ahmed Raza Zaqa,Marriam |
| publishDate | 2022 |
| publisher.none.fl_str_mv | Sociedade Portuguesa de Electroquímica |
| repo_facet_str | urn:repositoryAcronym:scielopt{{{_:::_}}}SciELO Portugal |
| reponame_str | SciELO Portugal |
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| spelling | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon ElectrodeMemon,Safia SanamWaris,MuhammadSidhu,Ahmed RazaZaqa,MarriamATRAuNPsGCE, sensorwastewateropen accesshttp://purl.org/coar/access_right/c_abf2http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042022000500363URLhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042022000500363URLHasVersion2022-10-01Abstract In this study, gold nanoparticles (AuNPs) were synthesized using sodium borohydride (NaBH4) as reductant. AuNPs size and shape were experimented by using various characterization techniques. The synthesized AuNPs performance capability for atrazine (ATR) detection, at a glassy carbon electrode (GCE), was verified using cyclic voltammetry (CV) as the determining mode. AuNPs impressive electrochemical performance and stability at the GCE led to further studies, without the need to apply nafion. ATR linear concentration plot ranged from 10 to 17 nM, with a lower limit of detection (LOD) of 0.17 nM, and a regression coefficient (R2) of 0.9934, under optimized conditions. The proposed sensor was very reliable, with a relative standard deviation (RSD) of 1.1%, for n = 20, and it was quite sensitive for ATR, with no discernible interference from other ions. Consequently, AuNPs were effectively used to identify ATR in several pesticide industry wastewater samples.Sociedade Portuguesa de ElectroquímicaPortugaliae Electrochimica Acta v.40 n.5 2022text/htmlengjournal articlehttp://purl.org/coar/resource_type/c_6501literature |
| spellingShingle | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode Memon,Safia Sanam ATR AuNPs GCE, sensor wastewater |
| status | SINGLETON |
| subject.fl_str_mv | ATR AuNPs GCE, sensor wastewater |
| title | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| title_full | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| title_fullStr | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| title_full_unstemmed | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| title_short | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| title_sort | Atrazine Voltammetric Determination in the Pesticide Industries Wastewater by Gold Nanoparticles at a Modified Glassy Carbon Electrode |
| topic | ATR AuNPs GCE, sensor wastewater |
| topic_facet | ATR AuNPs GCE, sensor wastewater |
| url | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042022000500363 |
| visible | 1 |
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