Publicação
High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions
| Resumo: | Lead-halide perovskite solar cells (PSCs) are currently the most promising emergent thin-film photovoltaic technology, having already reached power conversion efficiency (PCE) levels of state-of-the-art wafer-based silicon cells. The class of wide bandgap PSCs has also demonstrated high PCE values, thus becoming highly attractive for top sub-cells in tandem devices constructed with silicon or other types of bottom sub-cells. In this study, wide bandgap double-halide (Cs0.17FA0.83PbI3-xBrx) perovskite absorbers were developed with different bromine content, aiming to obtain bandgap values between 1.66 to 1.74 eV, by a glovebox-free (ambient) procedure. Low-cost inorganic materials, i.e. TiO2 and CuSCN, were used for the electron and hole transport layers, respectively. The 1.70 eV bandgap perovskite resulted in the highest reproducibility and stability (>80% initial PCE after 3500 hours) properties of the PSCs, remarkably attaining 16.4% PCE even with ambient and high humidity (∼70%) fabrication conditions. This journal is |
|---|---|
| Autores principais: | Menda, Ugur Deneb |
| Outros Autores: | Ribeiro, Guilherme; Nunes, Daniela; Calmeiro, Tomás; Águas, Hugo; Fortunato, Elvira; Martins, Rodrigo; Mendes, Manuel J. |
| Assunto: | General Materials Science Chemistry (miscellaneous) SDG 7 - Affordable and Clean Energy |
| Ano: | 2021 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | Universidade Nova de Lisboa |
| Idioma: | inglês |
| Origem: | Repositório Institucional da UNL |
| _version_ | 1879447141474107392 |
|---|---|
| author | Menda, Ugur Deneb |
| author2 | Ribeiro, Guilherme Nunes, Daniela Calmeiro, Tomás Águas, Hugo Fortunato, Elvira Martins, Rodrigo Mendes, Manuel J. |
| author2_role | author author author author author author author |
| author_facet | Menda, Ugur Deneb Ribeiro, Guilherme Nunes, Daniela Calmeiro, Tomás Águas, Hugo Fortunato, Elvira Martins, Rodrigo Mendes, Manuel J. |
| author_role | author |
| contributor_name_str_mv | DCM - Departamento de Ciência dos Materiais CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias RSC - Royal Society of Chemistry RUN |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Menda, Ugur Deneb\"},{\"Person.name\":\"Ribeiro, Guilherme\"},{\"Person.name\":\"Nunes, Daniela\"},{\"Person.name\":\"Calmeiro, Tomás\"},{\"Person.name\":\"Águas, Hugo\"},{\"Person.name\":\"Fortunato, Elvira\"},{\"Person.name\":\"Martins, Rodrigo\"},{\"Person.name\":\"Mendes, Manuel J.\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | DCM - Departamento de Ciência dos Materiais CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias RSC - Royal Society of Chemistry RUN |
| datacite.creators.creator.creatorName.fl_str_mv | Menda, Ugur Deneb Ribeiro, Guilherme Nunes, Daniela Calmeiro, Tomás Águas, Hugo Fortunato, Elvira Martins, Rodrigo Mendes, Manuel J. |
| datacite.date.Accepted.fl_str_mv | 2021-10-07T00:00:00Z |
| datacite.date.available.fl_str_mv | 2021-11-26T23:44:42Z |
| datacite.date.embargoed.fl_str_mv | 2021-11-26T23:44:42Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | General Materials Science Chemistry (miscellaneous) SDG 7 - Affordable and Clean Energy |
| datacite.titles.title.fl_str_mv | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| dc.contributor.none.fl_str_mv | DCM - Departamento de Ciência dos Materiais CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias RSC - Royal Society of Chemistry RUN |
| dc.creator.none.fl_str_mv | Menda, Ugur Deneb Ribeiro, Guilherme Nunes, Daniela Calmeiro, Tomás Águas, Hugo Fortunato, Elvira Martins, Rodrigo Mendes, Manuel J. |
| dc.date.Accepted.fl_str_mv | 2021-10-07T00:00:00Z |
| dc.date.available.fl_str_mv | 2021-11-26T23:44:42Z |
| dc.date.embargoed.fl_str_mv | 2021-11-26T23:44:42Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10362/128320 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | General Materials Science Chemistry (miscellaneous) SDG 7 - Affordable and Clean Energy |
| dc.title.fl_str_mv | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Lead-halide perovskite solar cells (PSCs) are currently the most promising emergent thin-film photovoltaic technology, having already reached power conversion efficiency (PCE) levels of state-of-the-art wafer-based silicon cells. The class of wide bandgap PSCs has also demonstrated high PCE values, thus becoming highly attractive for top sub-cells in tandem devices constructed with silicon or other types of bottom sub-cells. In this study, wide bandgap double-halide (Cs0.17FA0.83PbI3-xBrx) perovskite absorbers were developed with different bromine content, aiming to obtain bandgap values between 1.66 to 1.74 eV, by a glovebox-free (ambient) procedure. Low-cost inorganic materials, i.e. TiO2 and CuSCN, were used for the electron and hole transport layers, respectively. The 1.70 eV bandgap perovskite resulted in the highest reproducibility and stability (>80% initial PCE after 3500 hours) properties of the PSCs, remarkably attaining 16.4% PCE even with ambient and high humidity (∼70%) fabrication conditions. This journal is |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://run.unl.pt/bitstreams/3e66ec03-121c-49e2-8c23-715a98762f9f/download |
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| funding.funder.alternateName_str_mv | FCT FCT FCT FCT EC |
| funding.funder.identifier_str_mv | http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100008530 |
| funding.funder.name_str_mv | Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia European Commission |
| funding.identifier_str_mv | UIDB/50025/2020 PTDC/NAN-OPT/28430/2017 PTDC/NAN-OPT/28837/2017 UIDP/50025/2020 952169 |
| funding.name_str_mv | 6817 - DCRRNI ID 9471 - RIDTI 3599-PPCDT 6817 - DCRRNI ID H2020 |
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| identifier.url.fl_str_mv | http://hdl.handle.net/10362/128320 |
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| institution | Universidade Nova de Lisboa |
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| language | eng |
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| oai_identifier_str | oai:run.unl.pt:10362/128320 |
| organization_str_mv | urn:organizationAcronym:unl |
| person_str_mv | Menda, Ugur Deneb Ribeiro, Guilherme Nunes, Daniela Calmeiro, Tomás Águas, Hugo Fortunato, Elvira Martins, Rodrigo Mendes, Manuel J. |
| publishDate | 2021 |
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| spelling | engenLead-halide perovskite solar cells (PSCs) are currently the most promising emergent thin-film photovoltaic technology, having already reached power conversion efficiency (PCE) levels of state-of-the-art wafer-based silicon cells. The class of wide bandgap PSCs has also demonstrated high PCE values, thus becoming highly attractive for top sub-cells in tandem devices constructed with silicon or other types of bottom sub-cells. In this study, wide bandgap double-halide (Cs0.17FA0.83PbI3-xBrx) perovskite absorbers were developed with different bromine content, aiming to obtain bandgap values between 1.66 to 1.74 eV, by a glovebox-free (ambient) procedure. Low-cost inorganic materials, i.e. TiO2 and CuSCN, were used for the electron and hole transport layers, respectively. The 1.70 eV bandgap perovskite resulted in the highest reproducibility and stability (>80% initial PCE after 3500 hours) properties of the PSCs, remarkably attaining 16.4% PCE even with ambient and high humidity (∼70%) fabrication conditions. This journal isapplication/pdfenHigh-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditionsMenda, Ugur DenebRibeiro, GuilhermeNunes, DanielaCalmeiro, TomásÁguas, HugoFortunato, ElviraMartins, RodrigoMendes, Manuel J.DCM - Departamento de Ciência dos MateriaisCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)UNINOVA-Instituto de Desenvolvimento de Novas TecnologiasRSC - Royal Society of ChemistryHostingInstitutionOrganizationalRUNe-mailmailto:run@unl.ptrun@unl.ptISSNIsPartOf2633-5409URNIsPartOfPURE: 34379796URNIsPartOfPURE UUID: c36b7fe9-fe09-4a92-be28-db9df0b25a98URNIsPartOfScopus: 85116614626URNIsPartOfWOS: 000694976800001URNIsPartOfORCID: /0000-0002-7374-0726/work/103826590URNIsPartOfORCID: /0000-0001-7350-649X/work/103826772URNIsPartOfORCID: /0000-0003-3115-6588/work/103826824URNIsPartOfORCID: /0000-0002-4202-7047/work/103826837DOIIsPartOf10.1039/d1ma00432h2021-11-26T23:44:42Z2021-10-072021-10-07T00:00:00ZHandlehttp://hdl.handle.net/10362/128320http://purl.org/coar/access_right/c_abf2open accessGeneral Materials ScienceChemistry (miscellaneous)SDG 7 - Affordable and Clean Energy4861393 bytesFundação para a Ciência e a TecnologiaInstitute of Nanostructures, Nanomodelling and Nanofabricationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50025%2F2020/PTUIDB/50025/20206817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaSuperior Efficiency and Flexibility with Quantum Nano-structured Perovskite Solar Cells enhanced by Light Managementinfo:eu-repo/grantAgreement/FCT/9471 - RIDTI/PTDC%2FNAN-OPT%2F28430%2F2017/PTPTDC/NAN-OPT/28430/20179471 - RIDTICrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaTandem Solar Cells Improved Opticallyinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PTDC%2FNAN-OPT%2F28837%2F2017/PTPTDC/NAN-OPT/28837/20173599-PPCDTCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaInstitute of Nanostructures, Nanomodelling and Nanofabricationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50025%2F2020/PTUIDP/50025/20206817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871European CommissionSYmbiosis for eNERGY harversting concepts for smart platforms on foilsinfo:eu-repo/grantAgreement/EC/H2020/952169/EU952169H2020Crossref Funder IDhttp://doi.org/10.13039/501100008530literaturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://run.unl.pt/bitstreams/3e66ec03-121c-49e2-8c23-715a98762f9f/download |
| spellingShingle | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions Menda, Ugur Deneb General Materials Science Chemistry (miscellaneous) SDG 7 - Affordable and Clean Energy |
| status | SINGLETON |
| subject.fl_str_mv | General Materials Science Chemistry (miscellaneous) SDG 7 - Affordable and Clean Energy |
| title | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| title_full | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| title_fullStr | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| title_full_unstemmed | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| title_short | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| title_sort | High-performance wide bandgap perovskite solar cells fabricated in ambient high-humidity conditions |
| topic | General Materials Science Chemistry (miscellaneous) SDG 7 - Affordable and Clean Energy |
| topic_facet | General Materials Science Chemistry (miscellaneous) SDG 7 - Affordable and Clean Energy |
| url | http://hdl.handle.net/10362/128320 |
| visible | 1 |