Publication
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
| Summary: | The single-pot efficient oxidation of ethane to acetic acid catalysed by Au(I) or Au(III) compounds, chlorotriphenylphosphinegold(I) (1), chlorotrimethylphosphinegold(I) (2), 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) chloride (3), dichloro(2-pyridinecarboxylato)gold(III) (4), homogenous and supported on different carbon materials: activated carbon (AC), multi-walled carbon nanotubes (CNT) and carbon xerogel (CX), oxidised with nitric acid followed by treatment with NaOH (-ox-Na), is reported. The reactions were performed in water/acetonitrile. The materials were selective for the production of acetic acid, with no trace of by-products being detected. The best homogenous catalysts were complexes 2 and 3 which showed the highest ethane conversion and an acetic acid yield of ca. 21%, followed by 4 and 1. The heterogenised materials showed much better activity than the homogenous counterparts, with acetic acid yields up to 41.4% for 4@CNT-ox-Na, and remarkable selectivity (with acetic acid being the only product detected). The heterogenised catalysts with the best results were reused up to five cycles, with no significant loss of activity, and maintaining high selectivity for acetic acid. 4@CNT-ox-Na showed not only the best catalytic activity but also the best stability during the recycling runs. |
|---|---|
| Main Authors: | Ribeiro, Ana P. C. |
| Other Authors: | Matias, Inês A. S.; Carabineiro, Sónia A. C.; Martins, Luísa M. D. R. S. |
| Subject: | Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
| Year: | 2022 |
| Country: | Portugal |
| Document type: | article |
| Access type: | open access |
| Associated institution: | Universidade Nova de Lisboa |
| Language: | English |
| Origin: | Repositório Institucional da UNL |
| _version_ | 1879447553869611008 |
|---|---|
| author | Ribeiro, Ana P. C. |
| author2 | Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
| author2_role | author author author |
| author_facet | Ribeiro, Ana P. C. Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
| author_role | author |
| contributor_name_str_mv | LAQV@REQUIMTE DQ - Departamento de Química MDPI - Multidisciplinary Digital Publishing Institute RUN |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Ribeiro, Ana P. C.\"},{\"Person.name\":\"Matias, Inês A. S.\"},{\"Person.name\":\"Carabineiro, Sónia A. C.\"},{\"Person.name\":\"Martins, Luísa M. D. R. S.\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | LAQV@REQUIMTE DQ - Departamento de Química MDPI - Multidisciplinary Digital Publishing Institute RUN |
| datacite.creators.creator.creatorName.fl_str_mv | Ribeiro, Ana P. C. Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
| datacite.date.Accepted.fl_str_mv | 2022-02-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2022-02-17T23:19:48Z |
| datacite.date.embargoed.fl_str_mv | 2022-02-17T23:19:48Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
| datacite.titles.title.fl_str_mv | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| dc.contributor.none.fl_str_mv | LAQV@REQUIMTE DQ - Departamento de Química MDPI - Multidisciplinary Digital Publishing Institute RUN |
| dc.creator.none.fl_str_mv | Ribeiro, Ana P. C. Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
| dc.date.Accepted.fl_str_mv | 2022-02-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2022-02-17T23:19:48Z |
| dc.date.embargoed.fl_str_mv | 2022-02-17T23:19:48Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10362/133133 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
| dc.title.fl_str_mv | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | The single-pot efficient oxidation of ethane to acetic acid catalysed by Au(I) or Au(III) compounds, chlorotriphenylphosphinegold(I) (1), chlorotrimethylphosphinegold(I) (2), 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) chloride (3), dichloro(2-pyridinecarboxylato)gold(III) (4), homogenous and supported on different carbon materials: activated carbon (AC), multi-walled carbon nanotubes (CNT) and carbon xerogel (CX), oxidised with nitric acid followed by treatment with NaOH (-ox-Na), is reported. The reactions were performed in water/acetonitrile. The materials were selective for the production of acetic acid, with no trace of by-products being detected. The best homogenous catalysts were complexes 2 and 3 which showed the highest ethane conversion and an acetic acid yield of ca. 21%, followed by 4 and 1. The heterogenised materials showed much better activity than the homogenous counterparts, with acetic acid yields up to 41.4% for 4@CNT-ox-Na, and remarkable selectivity (with acetic acid being the only product detected). The heterogenised catalysts with the best results were reused up to five cycles, with no significant loss of activity, and maintaining high selectivity for acetic acid. 4@CNT-ox-Na showed not only the best catalytic activity but also the best stability during the recycling runs. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://run.unl.pt/bitstreams/73eec90f-e2b6-4048-822e-0e193695931c/download |
| id | run_cf56e9dcaab996bf04d2d561ede93a60 |
| identifier.url.fl_str_mv | http://hdl.handle.net/10362/133133 |
| inst_facet_str | urn:organizationAcronym:unl{{{_:::_}}}Universidade Nova de Lisboa |
| instacron_str | unl |
| institution | Universidade Nova de Lisboa |
| instname_str | Universidade Nova de Lisboa |
| language | eng |
| network_acronym_str | run |
| network_name_str | Repositório Institucional da UNL |
| oai_identifier_str | oai:run.unl.pt:10362/133133 |
| organization_str_mv | urn:organizationAcronym:unl |
| person_str_mv | Ribeiro, Ana P. C. Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
| publishDate | 2022 |
| repo_facet_str | urn:repositoryAcronym:run{{{_:::_}}}Repositório Institucional da UNL |
| reponame_str | Repositório Institucional da UNL |
| repository_id_str | urn:repositoryAcronym:run |
| service_str_mv | urn:repositoryAcronym:run |
| spelling | engenThe single-pot efficient oxidation of ethane to acetic acid catalysed by Au(I) or Au(III) compounds, chlorotriphenylphosphinegold(I) (1), chlorotrimethylphosphinegold(I) (2), 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) chloride (3), dichloro(2-pyridinecarboxylato)gold(III) (4), homogenous and supported on different carbon materials: activated carbon (AC), multi-walled carbon nanotubes (CNT) and carbon xerogel (CX), oxidised with nitric acid followed by treatment with NaOH (-ox-Na), is reported. The reactions were performed in water/acetonitrile. The materials were selective for the production of acetic acid, with no trace of by-products being detected. The best homogenous catalysts were complexes 2 and 3 which showed the highest ethane conversion and an acetic acid yield of ca. 21%, followed by 4 and 1. The heterogenised materials showed much better activity than the homogenous counterparts, with acetic acid yields up to 41.4% for 4@CNT-ox-Na, and remarkable selectivity (with acetic acid being the only product detected). The heterogenised catalysts with the best results were reused up to five cycles, with no significant loss of activity, and maintaining high selectivity for acetic acid. 4@CNT-ox-Na showed not only the best catalytic activity but also the best stability during the recycling runs.application/pdfenCommercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic AcidRibeiro, Ana P. C.Matias, Inês A. S.Carabineiro, Sónia A. C.Martins, Luísa M. D. R. S.LAQV@REQUIMTEDQ - Departamento de QuímicaMDPI - Multidisciplinary Digital Publishing InstituteHostingInstitutionOrganizationalRUNe-mailmailto:run@unl.ptrun@unl.ptISSNIsPartOf2073-4344URNIsPartOfPURE: 36734554URNIsPartOfPURE UUID: df9b2535-bd01-4db7-8187-8737140f3d27URNIsPartOfScopus: 85123540078URNIsPartOfORCID: /0000-0001-9913-4671/work/108412187URNIsPartOfWOS: 000770808200001DOIIsPartOf10.3390/catal120201652022-02-17T23:19:48Z2022-022022-02-01T00:00:00ZHandlehttp://hdl.handle.net/10362/133133http://purl.org/coar/access_right/c_abf2open accessAcetic acidCarbonEthane oxidationGoldHeterogeneous catalysisCatalysisPhysical and Theoretical Chemistry3124361 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://run.unl.pt/bitstreams/73eec90f-e2b6-4048-822e-0e193695931c/download |
| spellingShingle | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid Ribeiro, Ana P. C. Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
| status | SINGLETON |
| subject.fl_str_mv | Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
| title | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| title_full | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| title_fullStr | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| title_full_unstemmed | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| title_short | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| title_sort | Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
| topic | Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
| topic_facet | Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
| url | http://hdl.handle.net/10362/133133 |
| visible | 1 |
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