Publication
Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion
| Summary: | The urgent need for sustainable waste management strategies has led to the exploration of innovative approaches for the valorization of waste. In this study, a method is proposed for carbonizing waste biomass materials, particularly paper mill waste sludges (primary and biological) and knots, to produce porous carbonaceous supports. Through an initial hydrothermal carbonization followed by carbonization with nitrogen flow, porous carbon materials are successfully generated. The findings of this investigation validate the successful generation of effective carbonaceous supports utilizing waste biomass materials. These materials are then evaluated for their effectiveness as porous supports in the ionic liquid-catalyzed cycloaddition reaction of CO2 to styrene oxide, achieving a remarkable conversion rate of up to 98% and an impressive selectivity exceeding 99%. Additionally, the results underscore the significant impact of the selected IL on the overall conversion process. Overall, this study presents a promising pathway for the valorization of paper mill waste sludge through the production of porous carbon materials with potential applications in catalysis and beyond. |
|---|---|
| Main Authors: | Ribeiro, Mónica Stanton |
| Other Authors: | Lima, Maria M. R. A.; Vilarigues, Márcia; Zanatta, Marcileia; Corvo, Marta C. |
| Subject: | biomass carbonization CO cycloaddition ionic liquids paper mill sludge Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production SDG 13 - Climate Action |
| Year: | 2024 |
| Country: | Portugal |
| Document type: | article |
| Access type: | open access |
| Associated institution: | Universidade Nova de Lisboa |
| Language: | English |
| Origin: | Repositório Institucional da UNL |
| _version_ | 1879446745819119616 |
|---|---|
| author | Ribeiro, Mónica Stanton |
| author2 | Lima, Maria M. R. A. Vilarigues, Márcia Zanatta, Marcileia Corvo, Marta C. |
| author2_role | author author author author |
| author_facet | Ribeiro, Mónica Stanton Lima, Maria M. R. A. Vilarigues, Márcia Zanatta, Marcileia Corvo, Marta C. |
| author_role | author |
| contributor_name_str_mv | CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) DCM - Departamento de Ciência dos Materiais DCR - Departamento de Conservação e Restauro VICARTE - Vidro e Cerâmica para as Artes John Wiley and Sons Inc. RUN |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Ribeiro, Mónica Stanton\"},{\"Person.name\":\"Lima, Maria M. R. A.\"},{\"Person.name\":\"Vilarigues, Márcia\"},{\"Person.name\":\"Zanatta, Marcileia\"},{\"Person.name\":\"Corvo, Marta C.\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) DCM - Departamento de Ciência dos Materiais DCR - Departamento de Conservação e Restauro VICARTE - Vidro e Cerâmica para as Artes John Wiley and Sons Inc. RUN |
| datacite.creators.creator.creatorName.fl_str_mv | Ribeiro, Mónica Stanton Lima, Maria M. R. A. Vilarigues, Márcia Zanatta, Marcileia Corvo, Marta C. |
| datacite.date.Accepted.fl_str_mv | 2024-08-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2024-05-24T00:25:56Z |
| datacite.date.embargoed.fl_str_mv | 2024-05-24T00:25:56Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | biomass carbonization CO cycloaddition ionic liquids paper mill sludge Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production SDG 13 - Climate Action |
| datacite.titles.title.fl_str_mv | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| dc.contributor.none.fl_str_mv | CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N) DCM - Departamento de Ciência dos Materiais DCR - Departamento de Conservação e Restauro VICARTE - Vidro e Cerâmica para as Artes John Wiley and Sons Inc. RUN |
| dc.creator.none.fl_str_mv | Ribeiro, Mónica Stanton Lima, Maria M. R. A. Vilarigues, Márcia Zanatta, Marcileia Corvo, Marta C. |
| dc.date.Accepted.fl_str_mv | 2024-08-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2024-05-24T00:25:56Z |
| dc.date.embargoed.fl_str_mv | 2024-05-24T00:25:56Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/10362/167736 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.subject.none.fl_str_mv | biomass carbonization CO cycloaddition ionic liquids paper mill sludge Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production SDG 13 - Climate Action |
| dc.title.fl_str_mv | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | The urgent need for sustainable waste management strategies has led to the exploration of innovative approaches for the valorization of waste. In this study, a method is proposed for carbonizing waste biomass materials, particularly paper mill waste sludges (primary and biological) and knots, to produce porous carbonaceous supports. Through an initial hydrothermal carbonization followed by carbonization with nitrogen flow, porous carbon materials are successfully generated. The findings of this investigation validate the successful generation of effective carbonaceous supports utilizing waste biomass materials. These materials are then evaluated for their effectiveness as porous supports in the ionic liquid-catalyzed cycloaddition reaction of CO2 to styrene oxide, achieving a remarkable conversion rate of up to 98% and an impressive selectivity exceeding 99%. Additionally, the results underscore the significant impact of the selected IL on the overall conversion process. Overall, this study presents a promising pathway for the valorization of paper mill waste sludge through the production of porous carbon materials with potential applications in catalysis and beyond. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| fulltext.url.fl_str_mv | https://run.unl.pt/bitstreams/a253edc8-aadf-4a23-a085-e6060611dcdf/download |
| funder_facet_str_mv | FCT{{{_:::_}}}Fundação para a Ciência e a Tecnologia FCT{{{_:::_}}}Fundação para a Ciência e a Tecnologia |
| funding.funder.alternateName_str_mv | FCT FCT |
| funding.funder.identifier_str_mv | http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 |
| funding.funder.name_str_mv | Fundação para a Ciência e a Tecnologia Fundação para a Ciência e a Tecnologia |
| funding.identifier_str_mv | UIDB/00729/2020 UIDP/00729/2020 |
| funding.name_str_mv | 6817 - DCRRNI ID 6817 - DCRRNI ID |
| funding_str_mv | UIDB/00729/2020 info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00729%2F2020/PT UIDP/00729/2020 info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00729%2F2020/PT |
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| identifier.url.fl_str_mv | http://hdl.handle.net/10362/167736 |
| inst_facet_str | urn:organizationAcronym:unl{{{_:::_}}}Universidade Nova de Lisboa |
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| institution | Universidade Nova de Lisboa |
| instname_str | Universidade Nova de Lisboa |
| language | eng |
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| network_name_str | Repositório Institucional da UNL |
| oai_identifier_str | oai:run.unl.pt:10362/167736 |
| organization_str_mv | urn:organizationAcronym:unl |
| person_str_mv | Ribeiro, Mónica Stanton Lima, Maria M. R. A. Vilarigues, Márcia Zanatta, Marcileia Corvo, Marta C. |
| publishDate | 2024 |
| repo_facet_str | urn:repositoryAcronym:run{{{_:::_}}}Repositório Institucional da UNL |
| reponame_str | Repositório Institucional da UNL |
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| spelling | engenThe urgent need for sustainable waste management strategies has led to the exploration of innovative approaches for the valorization of waste. In this study, a method is proposed for carbonizing waste biomass materials, particularly paper mill waste sludges (primary and biological) and knots, to produce porous carbonaceous supports. Through an initial hydrothermal carbonization followed by carbonization with nitrogen flow, porous carbon materials are successfully generated. The findings of this investigation validate the successful generation of effective carbonaceous supports utilizing waste biomass materials. These materials are then evaluated for their effectiveness as porous supports in the ionic liquid-catalyzed cycloaddition reaction of CO2 to styrene oxide, achieving a remarkable conversion rate of up to 98% and an impressive selectivity exceeding 99%. Additionally, the results underscore the significant impact of the selected IL on the overall conversion process. Overall, this study presents a promising pathway for the valorization of paper mill waste sludge through the production of porous carbon materials with potential applications in catalysis and beyond.application/pdfenUpcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 ConversionRibeiro, Mónica StantonLima, Maria M. R. A.Vilarigues, MárciaZanatta, MarcileiaCorvo, Marta C.CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)DCM - Departamento de Ciência dos MateriaisDCR - Departamento de Conservação e RestauroVICARTE - Vidro e Cerâmica para as ArtesJohn Wiley and Sons Inc.HostingInstitutionOrganizationalRUNe-mailmailto:run@unl.ptrun@unl.ptISSNIsPartOf2366-7486URNIsPartOfPURE: 89349241URNIsPartOfPURE UUID: 9f81973b-85dd-4926-a080-c61c5253fe85URNIsPartOfScopus: 85190761094URNIsPartOfWOS: 001206237800001URNIsPartOfORCID: /0000-0002-3080-3627/work/168300187DOIIsPartOf10.1002/adsu.2023006552024-05-24T00:25:56Z2024-082024-08-01T00:00:00ZHandlehttp://hdl.handle.net/10362/167736http://purl.org/coar/access_right/c_abf2open accessbiomasscarbonizationCO cycloadditionionic liquidspaper mill sludgeRenewable Energy, Sustainability and the EnvironmentGeneral Environmental ScienceSDG 7 - Affordable and Clean EnergySDG 12 - Responsible Consumption and ProductionSDG 13 - Climate Action1844959 bytesFundação para a Ciência e a TecnologiaGlass and Ceramic for the Artsinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00729%2F2020/PTUIDB/00729/20206817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a TecnologiaGlass and Ceramic for the Artsinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00729%2F2020/PTUIDP/00729/20206817 - DCRRNI IDCrossref Funder IDhttp://doi.org/10.13039/501100001871literaturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_abf2application/pdffulltexthttps://run.unl.pt/bitstreams/a253edc8-aadf-4a23-a085-e6060611dcdf/download |
| spellingShingle | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion Ribeiro, Mónica Stanton biomass carbonization CO cycloaddition ionic liquids paper mill sludge Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production SDG 13 - Climate Action |
| status | SINGLETON |
| subject.fl_str_mv | biomass carbonization CO cycloaddition ionic liquids paper mill sludge Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production SDG 13 - Climate Action |
| title | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| title_full | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| title_fullStr | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| title_full_unstemmed | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| title_short | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| title_sort | Upcycling Waste Biomass–Production of Porous Carbonaceous Supports from Paper Mill Sludge and Application to CO2 Conversion |
| topic | biomass carbonization CO cycloaddition ionic liquids paper mill sludge Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production SDG 13 - Climate Action |
| topic_facet | biomass carbonization CO cycloaddition ionic liquids paper mill sludge Renewable Energy, Sustainability and the Environment General Environmental Science SDG 7 - Affordable and Clean Energy SDG 12 - Responsible Consumption and Production SDG 13 - Climate Action |
| url | http://hdl.handle.net/10362/167736 |
| visible | 1 |