Publication
Greener solvent-based processing of magnetoelectric nanocomposites
| Summary: | Polymer-based magnetoelectric (ME) nanocomposites are an enabling material technology for a wide range of applications in the area of digitalization strategies. Due to its highest piezoelectric response among polymers, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) is the piezoelectric matrix most used in polymer-based ME materials with over 80% of the total reports, with the resulting composites typically processed from solutions with N,N-dimethylformamide (DMF), a toxic solvent. Nevertheless, environmentally friendlier approaches and sustainable technologies are increasingly being required. This work demonstrates that P(VDF-TrFE)/Co2Fe2O4 nanocomposites can be successfully prepared from solution using three different environmentally friendlier solvents: dimethyl sulfoxide (DMSO), N,N′-dimethylpropyleneurea (DMPU), and triethyl phosphate (TEP) with different dipole moments. It is shown that the prepared composite films, with a maximum ME voltage coefficient of 35 mV cm–1 Oe–1 and a maximum sensitivity of 2.2 mV T–1, are suitable for applications, highlighting the path for a new generation of more sustainable ME sensors. |
|---|---|
| Main Authors: | Lima, A. C. |
| Other Authors: | Pereira, N.; Ribeiro, Clarisse Marta Oliveira; Lanceros-Méndez, S.; Martins, Pedro Libânio Abreu |
| Subject: | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| Year: | 2022 |
| Country: | Portugal |
| Document type: | article |
| Access type: | restricted access |
| Associated institution: | Universidade do Minho |
| Language: | English |
| Origin: | RepositóriUM - Universidade do Minho |
| _version_ | 1877774740287913984 |
|---|---|
| author | Lima, A. C. |
| author2 | Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| author2_role | author author author author |
| author_facet | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| author_role | author |
| contributor_name_str_mv | Universidade do Minho |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Lima, A. C.\"},{\"Person.name\":\"Pereira, N.\"},{\"Person.name\":\"Ribeiro, Clarisse Marta Oliveira\"},{\"Person.name\":\"Lanceros-Méndez, S.\"},{\"Person.name\":\"Martins, Pedro Libânio Abreu\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | Universidade do Minho |
| datacite.creators.creator.creatorName.fl_str_mv | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| datacite.date.Accepted.fl_str_mv | 2022-04-04T00:00:00Z |
| datacite.date.embargoed.fl_str_mv | 10000-01-01T00:00:00Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_16ec |
| datacite.subjects.subject.fl_str_mv | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| datacite.titles.title.fl_str_mv | Greener solvent-based processing of magnetoelectric nanocomposites |
| dc.contributor.none.fl_str_mv | Universidade do Minho |
| dc.creator.none.fl_str_mv | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| dc.date.Accepted.fl_str_mv | 2022-04-04T00:00:00Z |
| dc.date.embargoed.fl_str_mv | 10000-01-01T00:00:00Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | https://hdl.handle.net/1822/77024 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | American Chemical Society |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_16ec |
| dc.subject.none.fl_str_mv | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| dc.title.fl_str_mv | Greener solvent-based processing of magnetoelectric nanocomposites |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Polymer-based magnetoelectric (ME) nanocomposites are an enabling material technology for a wide range of applications in the area of digitalization strategies. Due to its highest piezoelectric response among polymers, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) is the piezoelectric matrix most used in polymer-based ME materials with over 80% of the total reports, with the resulting composites typically processed from solutions with N,N-dimethylformamide (DMF), a toxic solvent. Nevertheless, environmentally friendlier approaches and sustainable technologies are increasingly being required. This work demonstrates that P(VDF-TrFE)/Co2Fe2O4 nanocomposites can be successfully prepared from solution using three different environmentally friendlier solvents: dimethyl sulfoxide (DMSO), N,N′-dimethylpropyleneurea (DMPU), and triethyl phosphate (TEP) with different dipole moments. It is shown that the prepared composite films, with a maximum ME voltage coefficient of 35 mV cm–1 Oe–1 and a maximum sensitivity of 2.2 mV T–1, are suitable for applications, highlighting the path for a new generation of more sustainable ME sensors. |
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| funding.funder.identifier_str_mv | http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 http://doi.org/10.13039/501100001871 |
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| organization_str_mv | urn:organizationAcronym:repositorium |
| person_str_mv | Lima, A. C. Pereira, N. Ribeiro, Clarisse Marta Oliveira Lanceros-Méndez, S. Martins, Pedro Libânio Abreu |
| publishDate | 2022 |
| publisher.none.fl_str_mv | American Chemical Society |
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| spelling | engAmerican Chemical SocietyporPolymer-based magnetoelectric (ME) nanocomposites are an enabling material technology for a wide range of applications in the area of digitalization strategies. Due to its highest piezoelectric response among polymers, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) is the piezoelectric matrix most used in polymer-based ME materials with over 80% of the total reports, with the resulting composites typically processed from solutions with N,N-dimethylformamide (DMF), a toxic solvent. Nevertheless, environmentally friendlier approaches and sustainable technologies are increasingly being required. This work demonstrates that P(VDF-TrFE)/Co2Fe2O4 nanocomposites can be successfully prepared from solution using three different environmentally friendlier solvents: dimethyl sulfoxide (DMSO), N,N′-dimethylpropyleneurea (DMPU), and triethyl phosphate (TEP) with different dipole moments. It is shown that the prepared composite films, with a maximum ME voltage coefficient of 35 mV cm–1 Oe–1 and a maximum sensitivity of 2.2 mV T–1, are suitable for applications, highlighting the path for a new generation of more sustainable ME sensors.application/pdfporGreener solvent-based processing of magnetoelectric nanocompositesLima, A. C.Pereira, N.Ribeiro, Clarisse Marta OliveiraLanceros-Méndez, S.Martins, Pedro Libânio AbreuHostingInstitutionOrganizationalUniversidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptCITATIONLima, A. C., Pereira, N., Ribeiro, C., Lanceros-Mendez, S., & Martins, P. (2022, March 22). Greener Solvent-Based Processing of Magnetoelectric Nanocomposites. ACS Sustainable Chemistry & Engineering. American Chemical Society (ACS). http://doi.org/10.1021/acssuschemeng.1c06967ISSNIsPartOf2168-0485DOIIsPartOf10.1021/acssuschemeng.1c069672022-04-0410000-01-01T00:00:00Z2022-04-04T00:00:00ZHandlehttps://hdl.handle.net/1822/77024http://purl.org/coar/access_right/c_16ecrestricted accessCompositesPiezoelectricsNanoparticlesSolventsPolaritygreen manufacturing and engineeringnanoscience and nanotechnologygreen solventssustainable materialsmagnetoelectric791225 bytesFundação para a Ciência e a Tecnologia, I.P.Development of multifunctional inks for the implementation of interactive applications [SFRH/BD/131729/2017]https://hdl.handle.net/1822/100621SFRH/BD/131729/2017Crossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a Tecnologia, I.P.Development of advanced strategies and solutions for muscle tissue engineering based on electromechanical microenvironments [PTDC/BTM-MAT/28237/2017]Concurso para Financiamento de Projetos de Investigação Científica e Desenvolvimento Tecnológico em Todos os Domínios Científicos - 2017https://hdl.handle.net/1822/101323PTDC/BTM-MAT/28237/2017Crossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a Tecnologia, I.P.New inks for printed electronic components and sensing devices: integration into a fully printed magnetic sensor [SFRH/BD/132624/2017]https://hdl.handle.net/1822/103721SFRH/BD/132624/2017Crossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a Tecnologia, I.P.Biomimetic microenvironment for the study and development of targeted therapies in hematological malignancies [PTDC/EMD-EMD/28159/2017]Concurso para Financiamento de Projetos de Investigação Científica e Desenvolvimento Tecnológico em Todos os Domínios Científicos - 2017https://hdl.handle.net/1822/103336PTDC/EMD-EMD/28159/2017Crossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a Tecnologia, I.P.Physics Center of Minho and Porto Universities [UIDB/04650/2020]Concurso de avaliação no âmbito do Programa Plurianual de Financiamento de Unidades de I&D (2017/2018) - Financiamento Basehttps://hdl.handle.net/1822/97590UIDB/04650/2020Crossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a Tecnologia, I.P.E-Heart: Improving cardiac tissue regeneration through self-powered electroactive microenvironments [2020.04163.CEECIND/CP1600/CT0019]CEEC IND 3edhttps://hdl.handle.net/1822/1008742020.04163.CEECIND/CP1600/CT0019Crossref Funder IDhttp://doi.org/10.13039/501100001871Fundação para a Ciência e a Tecnologia, I.P.MagInk: Printable magnetic materials and devices [CEECIND/03975/2017/CP1458/CT0011]CEEC IND 2017https://hdl.handle.net/1822/101263CEECIND/03975/2017/CP1458/CT0011Crossref Funder IDhttp://doi.org/10.13039/501100001871literaturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_f1cfapplication/pdfhttps://repositorium.uminho.pt/bitstreams/a0c1e440-82c8-4290-9776-f200636b1c7e/download |
| spellingShingle | Greener solvent-based processing of magnetoelectric nanocomposites Lima, A. C. Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| status | SINGLETON |
| subject.fl_str_mv | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| title | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_full | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_fullStr | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_full_unstemmed | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_short | Greener solvent-based processing of magnetoelectric nanocomposites |
| title_sort | Greener solvent-based processing of magnetoelectric nanocomposites |
| topic | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| topic_facet | Composites Piezoelectrics Nanoparticles Solvents Polarity green manufacturing and engineering nanoscience and nanotechnology green solvents sustainable materials magnetoelectric |
| url | https://hdl.handle.net/1822/77024 |
| visible | 1 |