Publicação
Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability
| Resumo: | Electrospun poly(vinylidene fluoride) (PVDF) fiber mats find applications in an increasing number of areas, such as battery separators, filtration and detection membranes, due to their excellent properties. However, there are limitations due to the hydrophobic nature and low surface energy of PVDF. In this work, oxygen plasma treatment has been applied in order to modify the surface wettability of PVDF fiber mats and superhydrophilic PVDF electrospun membranes have been obtained. Further, plasma treatment does not significantly influences fiber average size (~400 ± 200 nm), morphology, electroactive -phase content (~80-85%) or the degree of crystallinity (Xc of 42 ± 2%), allowing to maintain the excellent physical-chemical characteristics of PVDF. Plasma treatment mainly induces surface chemistry modifications, such as the introduction of oxygen and release of fluorine atoms that significantly changes polymer membrane wettability by a reduction of the contact angle of the polymer fibers and an overall decrease of the surface tension of the membranes. |
|---|---|
| Autores principais: | Correia, D. M. |
| Outros Autores: | Ribeiro, C.; Sencadas, Vítor João Gomes Silva; Botelho, Gabriela; Carabineiro, S. A. C.; Ribelles, J. L. G.; Lanceros-Méndez, S. |
| Assunto: | Electrospun membranes Electroactive PVDF Oxygen plasma treatment Surface modification Surface wettability Oxidation mechanism Ciências Naturais::Ciências Físicas Ciências Naturais::Ciências Químicas |
| Ano: | 2015 |
| País: | Portugal |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso restrito |
| Instituição associada: | Universidade do Minho |
| Idioma: | inglês |
| Origem: | RepositóriUM - Universidade do Minho |
| _version_ | 1877774895929098240 |
|---|---|
| author | Correia, D. M. |
| author2 | Ribeiro, C. Sencadas, Vítor João Gomes Silva Botelho, Gabriela Carabineiro, S. A. C. Ribelles, J. L. G. Lanceros-Méndez, S. |
| author2_role | author author author author author author |
| author_facet | Correia, D. M. Ribeiro, C. Sencadas, Vítor João Gomes Silva Botelho, Gabriela Carabineiro, S. A. C. Ribelles, J. L. G. Lanceros-Méndez, S. |
| author_role | author |
| contributor_name_str_mv | RepositóriUM - Universidade do Minho |
| country_str | PT |
| creators_json_txt | [{\"Person.name\":\"Correia, D. M.\"},{\"Person.name\":\"Ribeiro, C.\"},{\"Person.name\":\"Sencadas, Vítor João Gomes Silva\"},{\"Person.name\":\"Botelho, Gabriela\"},{\"Person.name\":\"Carabineiro, S. A. C.\"},{\"Person.name\":\"Ribelles, J. L. G.\"},{\"Person.name\":\"Lanceros-Méndez, S.\"}] |
| datacite.contributors.contributor.contributorName.fl_str_mv | RepositóriUM - Universidade do Minho |
| datacite.creators.creator.creatorName.fl_str_mv | Correia, D. M. Ribeiro, C. Sencadas, Vítor João Gomes Silva Botelho, Gabriela Carabineiro, S. A. C. Ribelles, J. L. G. Lanceros-Méndez, S. |
| datacite.date.Accepted.fl_str_mv | 2015-01-01T00:00:00Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_16ec |
| datacite.subjects.subject.fl_str_mv | Electrospun membranes Electroactive PVDF Oxygen plasma treatment Surface modification Surface wettability Oxidation mechanism Ciências Naturais::Ciências Físicas Ciências Naturais::Ciências Químicas |
| datacite.titles.title.fl_str_mv | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| dc.contributor.none.fl_str_mv | RepositóriUM - Universidade do Minho |
| dc.creator.none.fl_str_mv | Correia, D. M. Ribeiro, C. Sencadas, Vítor João Gomes Silva Botelho, Gabriela Carabineiro, S. A. C. Ribelles, J. L. G. Lanceros-Méndez, S. |
| dc.date.Accepted.fl_str_mv | 2015-01-01T00:00:00Z |
| dc.format.none.fl_str_mv | application/pdf |
| dc.identifier.none.fl_str_mv | https://hdl.handle.net/1822/38766 |
| dc.language.none.fl_str_mv | eng |
| dc.publisher.none.fl_str_mv | Elsevier |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_16ec |
| dc.subject.none.fl_str_mv | Electrospun membranes Electroactive PVDF Oxygen plasma treatment Surface modification Surface wettability Oxidation mechanism Ciências Naturais::Ciências Físicas Ciências Naturais::Ciências Químicas |
| dc.title.fl_str_mv | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Electrospun poly(vinylidene fluoride) (PVDF) fiber mats find applications in an increasing number of areas, such as battery separators, filtration and detection membranes, due to their excellent properties. However, there are limitations due to the hydrophobic nature and low surface energy of PVDF. In this work, oxygen plasma treatment has been applied in order to modify the surface wettability of PVDF fiber mats and superhydrophilic PVDF electrospun membranes have been obtained. Further, plasma treatment does not significantly influences fiber average size (~400 ± 200 nm), morphology, electroactive -phase content (~80-85%) or the degree of crystallinity (Xc of 42 ± 2%), allowing to maintain the excellent physical-chemical characteristics of PVDF. Plasma treatment mainly induces surface chemistry modifications, such as the introduction of oxygen and release of fluorine atoms that significantly changes polymer membrane wettability by a reduction of the contact angle of the polymer fibers and an overall decrease of the surface tension of the membranes. |
| dirty | 0 |
| eu_rights_str_mv | restrictedAccess |
| format | article |
| id | rum_14ef0db68e15a4f273534ce3e4f44cb2 |
| identifier.url.fl_str_mv | https://hdl.handle.net/1822/38766 |
| inst_facet_str | urn:organizationAcronym:repositorium{{{_:::_}}}Universidade do Minho |
| instacron_str | repositorium |
| institution | Universidade do Minho |
| instname_str | Universidade do Minho |
| language | eng |
| network_acronym_str | rum |
| network_name_str | RepositóriUM - Universidade do Minho |
| oai_identifier_str | oai:repositorium.uminho.pt:1822/38766 |
| organization_str_mv | urn:organizationAcronym:repositorium |
| person_str_mv | Correia, D. M. Ribeiro, C. Sencadas, Vítor João Gomes Silva Botelho, Gabriela Carabineiro, S. A. C. Ribelles, J. L. G. Lanceros-Méndez, S. |
| publishDate | 2015 |
| publisher.none.fl_str_mv | Elsevier |
| repo_facet_str | urn:repositoryAcronym:rum{{{_:::_}}}RepositóriUM - Universidade do Minho |
| reponame_str | RepositóriUM - Universidade do Minho |
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| spelling | engElsevierporElectrospun poly(vinylidene fluoride) (PVDF) fiber mats find applications in an increasing number of areas, such as battery separators, filtration and detection membranes, due to their excellent properties. However, there are limitations due to the hydrophobic nature and low surface energy of PVDF. In this work, oxygen plasma treatment has been applied in order to modify the surface wettability of PVDF fiber mats and superhydrophilic PVDF electrospun membranes have been obtained. Further, plasma treatment does not significantly influences fiber average size (~400 ± 200 nm), morphology, electroactive -phase content (~80-85%) or the degree of crystallinity (Xc of 42 ± 2%), allowing to maintain the excellent physical-chemical characteristics of PVDF. Plasma treatment mainly induces surface chemistry modifications, such as the introduction of oxygen and release of fluorine atoms that significantly changes polymer membrane wettability by a reduction of the contact angle of the polymer fibers and an overall decrease of the surface tension of the membranes.application/pdfporInfluence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettabilityCorreia, D. M.Ribeiro, C.Sencadas, Vítor João Gomes SilvaBotelho, GabrielaCarabineiro, S. A. C.Ribelles, J. L. G.Lanceros-Méndez, S.HostingInstitutionOrganizationalRepositóriUM - Universidade do Minhoe-mailmailto:repositorium@usdb.uminho.ptrepositorium@usdb.uminho.ptCITATIONCorreia, D. M., Ribeiro, C., Sencadas, V., Botelho, G., Carabineiro, S. A. C., Ribelles, J. L. G., & Lanceros-Méndez, S. (2015). Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability. Progress in Organic Coatings, 85, 151-158. doi: 10.1016/j.porgcoat.2015.03.019ISSNIsPartOf0300-9440DOIIsPartOf10.1016/j.porgcoat.2015.03.01920152015-01-01T00:00:00ZHandlehttps://hdl.handle.net/1822/38766http://purl.org/coar/access_right/c_16ecrestricted accessElectrospun membranesElectroactive PVDFOxygen plasma treatmentSurface modificationSurface wettabilityOxidation mechanismhttp://www.oecd.org/science/inno/38235147.pdfFields of Science and Technology (FOS)Ciências Naturais::Ciências Físicashttp://www.oecd.org/science/inno/38235147.pdfFields of Science and Technology (FOS)Ciências Naturais::Ciências Químicas1163289 bytesliteraturehttp://purl.org/coar/resource_type/c_6501journal articlehttp://purl.org/coar/access_right/c_16ecapplication/pdfhttps://repositorium.uminho.pt/bitstreams/27cd23c2-1fb3-4c5f-94d9-efbcddf4a112/download |
| spellingShingle | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability Correia, D. M. Electrospun membranes Electroactive PVDF Oxygen plasma treatment Surface modification Surface wettability Oxidation mechanism Ciências Naturais::Ciências Físicas Ciências Naturais::Ciências Químicas |
| status | SINGLETON |
| subject.fl_str_mv | Electrospun membranes Electroactive PVDF Oxygen plasma treatment Surface modification Surface wettability Oxidation mechanism |
| subject.other.fl_str_mv | Ciências Naturais::Ciências Físicas Ciências Naturais::Ciências Químicas |
| title | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| title_full | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| title_fullStr | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| title_full_unstemmed | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| title_short | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| title_sort | Influence of oxygen plasma treatment parameters on poly(vinylidene fluoride) electrospun fiber mats wettability |
| topic | Electrospun membranes Electroactive PVDF Oxygen plasma treatment Surface modification Surface wettability Oxidation mechanism Ciências Naturais::Ciências Físicas Ciências Naturais::Ciências Químicas |
| topic_facet | Electrospun membranes Electroactive PVDF Oxygen plasma treatment Surface modification Surface wettability Oxidation mechanism Ciências Naturais::Ciências Físicas Ciências Naturais::Ciências Químicas |
| url | https://hdl.handle.net/1822/38766 |
| visible | 1 |
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