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Aqueous tape casting of micro and nano YSZ for SOFC electrolytes

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Resumo:Yttria-stabilized zirconia (YSZ) thick films with similar to 95% relative density were produced by aqueous tape casting to be used as electrolytes in solid oxide fuel cells (SOFC). Structural and morphologic properties of green and sintered bodies were analyzed starting from different particle size 8% yttria-stabilized zirconia powders. XRD showed the precursor powders to be single phase and nanocrystqlline with composition within the expected range for cubic YSZ. Grain size distribution and specific area measurements confirmed the micrometer and nanometer range of the particles. Before casting, slurries were formulated based on rheological characterization, zeta potential and pH measurements. A relationship between starting powders, ceramic suspensions and sintered bodies was established and adapted to the tape casting process. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
Autores principais:Baquero, Tomas
Outros Autores:Escobar, Jairo; Frade, Jorge; Hotza, Dachamir
Assunto:OXIDE FUEL-CELLS YTTRIA-STABILIZED ZIRCONIA
Ano:2013
País:Portugal
Tipo de documento:artigo
Tipo de acesso:acesso restrito
Instituição associada:Universidade de Aveiro
Idioma:inglês
Origem:RIA - Repositório Institucional da Universidade de Aveiro
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author Baquero, Tomas
author2 Escobar, Jairo
Frade, Jorge
Hotza, Dachamir
author2_role author
author
author
author_facet Baquero, Tomas
Escobar, Jairo
Frade, Jorge
Hotza, Dachamir
author_role author
country_str PT
creators_json_txt [{\"Person.name\":\"Baquero, Tomas\"},{\"Person.name\":\"Escobar, Jairo\"},{\"Person.name\":\"Frade, Jorge\"},{\"Person.name\":\"Hotza, Dachamir\"}]
datacite.creators.creator.creatorName.fl_str_mv Baquero, Tomas
Escobar, Jairo
Frade, Jorge
Hotza, Dachamir
datacite.date.Accepted.fl_str_mv 2013-01-01T00:00:00Z
datacite.date.embargoed.fl_str_mv 10000-01-01T00:00:00Z
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_16ec
datacite.subjects.subject.fl_str_mv OXIDE FUEL-CELLS
YTTRIA-STABILIZED ZIRCONIA
datacite.titles.title.fl_str_mv Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
dc.creator.none.fl_str_mv Baquero, Tomas
Escobar, Jairo
Frade, Jorge
Hotza, Dachamir
dc.date.Accepted.fl_str_mv 2013-01-01T00:00:00Z
dc.date.embargoed.fl_str_mv 10000-01-01T00:00:00Z
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv http://hdl.handle.net/10773/20385
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv ELSEVIER SCI LTD
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_16ec
dc.subject.none.fl_str_mv OXIDE FUEL-CELLS
YTTRIA-STABILIZED ZIRCONIA
dc.title.fl_str_mv Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description Yttria-stabilized zirconia (YSZ) thick films with similar to 95% relative density were produced by aqueous tape casting to be used as electrolytes in solid oxide fuel cells (SOFC). Structural and morphologic properties of green and sintered bodies were analyzed starting from different particle size 8% yttria-stabilized zirconia powders. XRD showed the precursor powders to be single phase and nanocrystqlline with composition within the expected range for cubic YSZ. Grain size distribution and specific area measurements confirmed the micrometer and nanometer range of the particles. Before casting, slurries were formulated based on rheological characterization, zeta potential and pH measurements. A relationship between starting powders, ceramic suspensions and sintered bodies was established and adapted to the tape casting process. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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inst_facet_str urn:organizationAcronym:ua{{{_:::_}}}Universidade de Aveiro
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institution Universidade de Aveiro
instname_str Universidade de Aveiro
language eng
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oai_identifier_str oai:ria.ua.pt:10773/20385
organization_str_mv urn:organizationAcronym:ua
person_str_mv Baquero, Tomas
Escobar, Jairo
Frade, Jorge
Hotza, Dachamir
publishDate 2013
publisher.none.fl_str_mv ELSEVIER SCI LTD
repo_facet_str urn:repositoryAcronym:ria{{{_:::_}}}RIA - Repositório Institucional da Universidade de Aveiro
reponame_str RIA - Repositório Institucional da Universidade de Aveiro
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spelling porYttria-stabilized zirconia (YSZ) thick films with similar to 95% relative density were produced by aqueous tape casting to be used as electrolytes in solid oxide fuel cells (SOFC). Structural and morphologic properties of green and sintered bodies were analyzed starting from different particle size 8% yttria-stabilized zirconia powders. XRD showed the precursor powders to be single phase and nanocrystqlline with composition within the expected range for cubic YSZ. Grain size distribution and specific area measurements confirmed the micrometer and nanometer range of the particles. Before casting, slurries were formulated based on rheological characterization, zeta potential and pH measurements. A relationship between starting powders, ceramic suspensions and sintered bodies was established and adapted to the tape casting process. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.application/pdfengELSEVIER SCI LTDporAqueous tape casting of micro and nano YSZ for SOFC electrolytesBaquero, TomasEscobar, JairoFrade, JorgeHotza, DachamirHandlehttp://hdl.handle.net/10773/20385ISSNIsPartOf0272-8842DOIIsPartOf10.1016/j.ceramint.2013.03.09710000-01-01T00:00:00Z2013-01-01T00:00:00Z2013http://purl.org/coar/access_right/c_16ecrestricted accessporOXIDE FUEL-CELLSporYTTRIA-STABILIZED ZIRCONIA2750301 byteshttp://purl.org/coar/access_right/c_16ecapplication/pdffulltexthttps://ria.ua.pt/bitstream/10773/20385/2/Aqueous%20tape%20casting%20of%20micro%20and%20nano%20YSZ%20for%20SOFC%20electrolytes_10.1016j.ceramint.2013.03.097.pdfliteraturehttp://purl.org/coar/resource_type/c_6501journal article
spellingShingle Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
Baquero, Tomas
OXIDE FUEL-CELLS
YTTRIA-STABILIZED ZIRCONIA
status SINGLETON
subject.fl_str_mv OXIDE FUEL-CELLS
YTTRIA-STABILIZED ZIRCONIA
title Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
title_full Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
title_fullStr Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
title_full_unstemmed Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
title_short Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
title_sort Aqueous tape casting of micro and nano YSZ for SOFC electrolytes
topic OXIDE FUEL-CELLS
YTTRIA-STABILIZED ZIRCONIA
topic_facet OXIDE FUEL-CELLS
YTTRIA-STABILIZED ZIRCONIA
url http://hdl.handle.net/10773/20385
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