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Thermal behaviour and isothermal kinetics of rhodium(II) acetate.

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Resumo:The thermal decomposition of solid rhodium(II) acetate was studied by isothermal TG. Kinetic analysis of the isothermal data showed that the complex decomposition in the range 198.0-210.5°C occurs according to a Prout-Tompkins (An) law. The isothermal curves are better fitted using a non-linear least square method. The activation energy found was 16:2.7 kJ tool ~. At temperatures higher than 210.5°C the decomposition is strongly accelerated and no kinetic study was available.
Autores principais:Carvalho, Cornélio de Freitas
Outros Autores:Braga, M. M.; Yoshida, Maria Irene; Sinisterra, Ruben Dario
Assunto:Thermal decomposition Isothermal Kinetics Mechanism Rhodium(II) carboxylates
Ano:2012
País:Brasil
Tipo de documento:artigo
Tipo de acesso:unknown
Instituição associada:IBICT
Idioma:inglês
Origem:Oasisbr

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