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INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN

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Summary:AbstractThe components of fusel oil form azeotropes with water, resulting in challenges in obtaining hydrous ethanol fuel (HEF) and increasing investment and operating costs. The aim of this study was to evaluate how the presence of fusel oil affected HEF distillation. Mixtures of ethanol (6.0 to 6.5 % w/w) and water (93.0 to 94 % w/w) containing different concentrations (zero to 0.5 % w/w) of 3-methyl-1-butanol, 2-methyl-1-propanol, propan-1-ol and propan-2-ol were distilled in a laboratory apparatus. Under total reflux conditions, HEF concentrations in compliance with Brazilian legislation specifications were obtained, but the desired concentration could not be attained under continuous operation. All of the experiments resulted in a high loss of ethanol in the bottom product under multiple operating conditions. The results demonstrated that fusel oil affects HEF distillation, but that HEF concentrations can still be obtained in compliance with Brazilian legislation.
Main Authors:Mayer,F. D.
Other Authors:Feris,L. A.; Marcilio,N. R.; Staudt,P. B.; Hoffmann,R.; Baldo,V.
Subject:Fuel ethanol Distillation Fusel oil
Year:2015
Country:Brazil
Document type:article
Access type:open access
Associated institution:IBICT
Language:English
Origin:Oasisbr
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author Mayer,F. D.
author2 Feris,L. A.
Marcilio,N. R.
Staudt,P. B.
Hoffmann,R.
Baldo,V.
author2_role author
author
author
author
author
author_facet Mayer,F. D.
Feris,L. A.
Marcilio,N. R.
Staudt,P. B.
Hoffmann,R.
Baldo,V.
author_role author
country_str BR
creators_json_txt [{\"Person.name\":\"Mayer,F. D.\"},{\"Person.name\":\"Feris,L. A.\"},{\"Person.name\":\"Marcilio,N. R.\"},{\"Person.name\":\"Staudt,P. B.\"},{\"Person.name\":\"Hoffmann,R.\"},{\"Person.name\":\"Baldo,V.\"}]
datacite.creators.creator.creatorName.fl_str_mv Mayer,F. D.
Feris,L. A.
Marcilio,N. R.
Staudt,P. B.
Hoffmann,R.
Baldo,V.
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Fuel ethanol
Distillation
Fusel oil
datacite.titles.title.fl_str_mv INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
dc.creator.none.fl_str_mv Mayer,F. D.
Feris,L. A.
Marcilio,N. R.
Staudt,P. B.
Hoffmann,R.
Baldo,V.
dc.format.none.fl_str_mv text/html
dc.identifier.none.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200585
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.source.none.fl_str_mv Brazilian Journal of Chemical Engineering v.32 n.2 2015
reponame:Brazilian Journal of Chemical Engineering
instname:Associação Brasileira de Engenharia Química (ABEQ)
instacron:ABEQ
dc.subject.none.fl_str_mv Fuel ethanol
Distillation
Fusel oil
dc.title.fl_str_mv INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description AbstractThe components of fusel oil form azeotropes with water, resulting in challenges in obtaining hydrous ethanol fuel (HEF) and increasing investment and operating costs. The aim of this study was to evaluate how the presence of fusel oil affected HEF distillation. Mixtures of ethanol (6.0 to 6.5 % w/w) and water (93.0 to 94 % w/w) containing different concentrations (zero to 0.5 % w/w) of 3-methyl-1-butanol, 2-methyl-1-propanol, propan-1-ol and propan-2-ol were distilled in a laboratory apparatus. Under total reflux conditions, HEF concentrations in compliance with Brazilian legislation specifications were obtained, but the desired concentration could not be attained under continuous operation. All of the experiments resulted in a high loss of ethanol in the bottom product under multiple operating conditions. The results demonstrated that fusel oil affects HEF distillation, but that HEF concentrations can still be obtained in compliance with Brazilian legislation.
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person_str_mv Mayer,F. D.
Feris,L. A.
Marcilio,N. R.
Staudt,P. B.
Hoffmann,R.
Baldo,V.
publishDate 2015
publisher.none.fl_str_mv Brazilian Society of Chemical Engineering
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spelling INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMNMayer,F. D.Feris,L. A.Marcilio,N. R.Staudt,P. B.Hoffmann,R.Baldo,V.Fuel ethanolDistillationFusel oilopen accesshttp://purl.org/coar/access_right/c_abf2http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200585URLhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200585URLHasVersion2015-06-01AbstractThe components of fusel oil form azeotropes with water, resulting in challenges in obtaining hydrous ethanol fuel (HEF) and increasing investment and operating costs. The aim of this study was to evaluate how the presence of fusel oil affected HEF distillation. Mixtures of ethanol (6.0 to 6.5 % w/w) and water (93.0 to 94 % w/w) containing different concentrations (zero to 0.5 % w/w) of 3-methyl-1-butanol, 2-methyl-1-propanol, propan-1-ol and propan-2-ol were distilled in a laboratory apparatus. Under total reflux conditions, HEF concentrations in compliance with Brazilian legislation specifications were obtained, but the desired concentration could not be attained under continuous operation. All of the experiments resulted in a high loss of ethanol in the bottom product under multiple operating conditions. The results demonstrated that fusel oil affects HEF distillation, but that HEF concentrations can still be obtained in compliance with Brazilian legislation.engtext/htmlBrazilian Society of Chemical EngineeringBrazilian Journal of Chemical Engineering v.32 n.2 2015reponame:Brazilian Journal of Chemical Engineeringinstname:Associação Brasileira de Engenharia Química (ABEQ)instacron:ABEQjournal articlehttp://purl.org/coar/resource_type/c_6501literatureVoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85
spellingShingle INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
Mayer,F. D.
Fuel ethanol
Distillation
Fusel oil
status SINGLETON
status_str VoR
subject.fl_str_mv Fuel ethanol
Distillation
Fusel oil
title INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
title_full INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
title_fullStr INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
title_full_unstemmed INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
title_short INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
title_sort INFLUENCE OF FUSEL OIL COMPONENTS ON THE DISTILLATION OF HYDROUS ETHANOL FUEL (HEF) IN A BENCH COLUMN
topic Fuel ethanol
Distillation
Fusel oil
topic_facet Fuel ethanol
Distillation
Fusel oil
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000200585
visible 1

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