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Porous carbon obtained by the pyrolysis of TiO2/poly(furfuryl alcohol) nanocomposite: preparation, characterization and utilization for adsorption of reactive dyes from aqueous solution

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Summary:This study reports the preparation of high surface area amorphous carbon by pyrolysis of TiO2/poly(furfuryl alcohol) nanocomposite. This nanocomposite was synthesized by hydrolysis of titanium tetra-isopropoxide/furfuryl alcohol mixture. All samples were characterized by XRD, FT-IR, Raman spectroscopy and transmission electron microscopy. The results indicated the effective FA polymerization on TiO2 (anatase) nanoparticles and polymer conversion to amorphous carbon after pyrolysis, simultaneously with TiO2 anatase-rutile phase transition. After the oxide nanoparticles dissolution by an aqueous HF solution the obtained carbon was extremely porous, with high surface area (700 m² g-1), similar to a carbon foam. With this new carbon material we carried out a study of kinetic of the adsorption of the reactive black 5 (RB5) azo-dye.
Main Authors:Almeida Filho,Cláudio de
Other Authors:Zarbin,Aldo J. G.
Subject:porous carbon nanocomposites TiO2 poly(furfuryl alcohol) sol-gel
Year:2006
Country:Brazil
Document type:article
Access type:open access
Associated institution:IBICT
Language:English
Origin:Oasisbr

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