Publicação
New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate
| Resumo: | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) |
|---|---|
| Autores principais: | Carvalho, Suzana Gonçalves |
| Outros Autores: | dos Santos, Aline Martins; Silvestre, Amanda Letícia Polli; Meneguin, Andréia Bagliotti; Ferreira, Leonardo Miziara Barboza; Chorilli, Marlus; Gremião, Maria Palmira Daflon |
| Assunto: | Chitosan Chitosan oligosaccharide Dextran sulfate Molecular weight Nanoparticles Polyelectrolyte complexation |
| Ano: | 2022 |
| País: | Brasil |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | IBICT |
| Idioma: | inglês |
| Origem: | Oasisbr |
| _version_ | 1871601212905750528 |
|---|---|
| author | Carvalho, Suzana Gonçalves |
| author2 | dos Santos, Aline Martins Silvestre, Amanda Letícia Polli Meneguin, Andréia Bagliotti Ferreira, Leonardo Miziara Barboza Chorilli, Marlus Gremião, Maria Palmira Daflon |
| author2_role | author author author author author author |
| author_facet | Carvalho, Suzana Gonçalves dos Santos, Aline Martins Silvestre, Amanda Letícia Polli Meneguin, Andréia Bagliotti Ferreira, Leonardo Miziara Barboza Chorilli, Marlus Gremião, Maria Palmira Daflon |
| author_role | author |
| country_str | BR |
| creators_json_txt | [{\"Person.name\":\"Carvalho, Suzana Gonçalves\"},{\"Person.name\":\"dos Santos, Aline Martins\"},{\"Person.name\":\"Silvestre, Amanda Letícia Polli\"},{\"Person.name\":\"Meneguin, Andréia Bagliotti\"},{\"Person.name\":\"Ferreira, Leonardo Miziara Barboza\"},{\"Person.name\":\"Chorilli, Marlus\"},{\"Person.name\":\"Gremião, Maria Palmira Daflon\"}] |
| datacite.creators.creator.creatorName.fl_str_mv | Carvalho, Suzana Gonçalves dos Santos, Aline Martins Silvestre, Amanda Letícia Polli Meneguin, Andréia Bagliotti Ferreira, Leonardo Miziara Barboza Chorilli, Marlus Gremião, Maria Palmira Daflon |
| datacite.date.Accepted.fl_str_mv | 2021-11-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2022-05-01T06:02:34Z |
| datacite.date.embargoed.fl_str_mv | 2022-05-01T06:02:34Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | Chitosan Chitosan oligosaccharide Dextran sulfate Molecular weight Nanoparticles Polyelectrolyte complexation |
| datacite.titles.title.fl_str_mv | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| dc.creator.none.fl_str_mv | Carvalho, Suzana Gonçalves dos Santos, Aline Martins Silvestre, Amanda Letícia Polli Meneguin, Andréia Bagliotti Ferreira, Leonardo Miziara Barboza Chorilli, Marlus Gremião, Maria Palmira Daflon |
| dc.date.Accepted.fl_str_mv | 2021-11-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2022-05-01T06:02:34Z |
| dc.date.embargoed.fl_str_mv | 2022-05-01T06:02:34Z |
| dc.description.none.fl_str_mv | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Universidade Estadual Paulista Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Processo FAPESP: 2019/10761-5 Polyelectrolyte complexation is a technique based on interactions between polyelectrolytes of opposite charges driven by supramolecular interactions. Although many studies address the formation of polyelectrolyte complexes (PECs), few explore strategies and tools to select the best working conditions and are often based on empirical choices. This study evaluates the influence of pH, molecular weight, and polymeric proportion on the formation of PECs based on chitosan:dextran sulfate. In addition, it assesses the approaches that study the influence of pH on the zeta potential of polymeric dispersions as a tool in the design of PECs. Results showed that nanoparticles with an excess of polycation formed aggregates, while an excess of dextran sulfate reduced the size of the particles. The graph of zeta potential as a function of pH proved to be a promising tool in the choice of polymers and a better pH condition in the development of PECs. |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/11449/233269 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.source.none.fl_str_mv | reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
| dc.subject.none.fl_str_mv | Chitosan Chitosan oligosaccharide Dextran sulfate Molecular weight Nanoparticles Polyelectrolyte complexation |
| dc.title.fl_str_mv | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| id | oasisbr_b34ba7dbe68bbcadf8767b79a74dd06a |
| identifier.url.fl_str_mv | http://hdl.handle.net/11449/233269 |
| inst_facet_str | urn:organizationAcronym:oasisbr{{{_:::_}}}IBICT |
| instacron_str | OASISBR |
| institution | IBICT |
| instname_str | IBICT |
| language | eng |
| network_acronym_str | oasisbr |
| network_name_str | Oasisbr |
| oai_identifier_str | oai:repositorio.unesp.br:11449/233269 |
| organization_str_mv | urn:organizationAcronym:oasisbr |
| person_str_mv | Carvalho, Suzana Gonçalves dos Santos, Aline Martins Silvestre, Amanda Letícia Polli Meneguin, Andréia Bagliotti Ferreira, Leonardo Miziara Barboza Chorilli, Marlus Gremião, Maria Palmira Daflon |
| publishDate | 2022 |
| repo_facet_str | urn:repositoryAcronym:oasisbr{{{_:::_}}}Oasisbr |
| reponame_str | Oasisbr |
| repository_id_str | urn:repositoryAcronym:oasisbr |
| service_str_mv | urn:repositoryAcronym:oasisbr |
| spelling | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfateCarvalho, Suzana Gonçalvesdos Santos, Aline MartinsSilvestre, Amanda Letícia PolliMeneguin, Andréia BagliottiFerreira, Leonardo Miziara BarbozaChorilli, MarlusGremião, Maria Palmira DaflonChitosanChitosan oligosaccharideDextran sulfateMolecular weightNanoparticlesPolyelectrolyte complexationopen accesshttp://purl.org/coar/access_right/c_abf2http://hdl.handle.net/11449/233269HandleCarbohydrate Polymers, v. 271.N/AHasVersion0144-8617N/AHasVersion2-s2.0-85110276829N/AHasVersionhttps://doi.org/http://dx.doi.org/10.1016/j.carbpol.2021.118436DOIhttp://hdl.handle.net/11449/233269Handlehttps://doi.org/10.1016/j.carbpol.2021.118436DOI2022-05-01T06:02:34Z2022-05-012021-11-01T00:00:00ZCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Universidade Estadual PaulistaFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Processo FAPESP: 2019/10761-5Polyelectrolyte complexation is a technique based on interactions between polyelectrolytes of opposite charges driven by supramolecular interactions. Although many studies address the formation of polyelectrolyte complexes (PECs), few explore strategies and tools to select the best working conditions and are often based on empirical choices. This study evaluates the influence of pH, molecular weight, and polymeric proportion on the formation of PECs based on chitosan:dextran sulfate. In addition, it assesses the approaches that study the influence of pH on the zeta potential of polymeric dispersions as a tool in the design of PECs. Results showed that nanoparticles with an excess of polycation formed aggregates, while an excess of dextran sulfate reduced the size of the particles. The graph of zeta potential as a function of pH proved to be a promising tool in the choice of polymers and a better pH condition in the development of PECs.engreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPjournal articlehttp://purl.org/coar/resource_type/c_6501literatureVoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85 |
| spellingShingle | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate Carvalho, Suzana Gonçalves Chitosan Chitosan oligosaccharide Dextran sulfate Molecular weight Nanoparticles Polyelectrolyte complexation |
| status | SINGLETON |
| status_str | VoR |
| subject.fl_str_mv | Chitosan Chitosan oligosaccharide Dextran sulfate Molecular weight Nanoparticles Polyelectrolyte complexation |
| title | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| title_full | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| title_fullStr | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| title_full_unstemmed | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| title_short | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| title_sort | New insights into physicochemical aspects involved in the formation of polyelectrolyte complexes based on chitosan and dextran sulfate |
| topic | Chitosan Chitosan oligosaccharide Dextran sulfate Molecular weight Nanoparticles Polyelectrolyte complexation |
| topic_facet | Chitosan Chitosan oligosaccharide Dextran sulfate Molecular weight Nanoparticles Polyelectrolyte complexation |
| url | http://hdl.handle.net/11449/233269 |
| visible | 1 |
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