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Chitosan Nanocomposites with Graphene-Based Filler

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Summary:This study evaluates the properties of chitosan (CS) membranes modified with different percentages (0.5%, 3%, and 5% w/w) of a graphene-based material. Graphene oxide (GO) and reduced graphene oxide (RGO) were obtained by the chemical exfoliation of graphite and thermal reduction. Then, they were characterized by electrical conductivity measurements, FESEM, XRD, AFM, and Raman spectroscopy. The composites’ morphology was evaluated by FESEM. The degree of swelling over a 48 h period and mass loss behavior in phosphate-buffered saline solution for up to 70 days were also studied. The hydrophilicity of the CS and CS/graphene nanocomposites was examined by water contact angle. The graphene materials showed small stacks (6-8 sheets) with low defect density and nanoscale thickness (1.3-5.9 nm). The dispersion of the graphene material in the CS matrix significantly decreased the degree of swelling (460%) but did not modify the hydrolytic degradation process and the hydrophilicity of membranes.
Main Authors:Maraschin,Thuany Garcia
Other Authors:Correa,Roberto da Silva; Rodrigues,Luiz Frederico; Balzarettid,Naira Maria; Malmonge,José Antonio; Galland,Griselda Barrera; Basso,Nara Regina de Souza
Subject:Graphene oxide reduced graphene oxide, chitosan biodegradable polymer
Year:2019
Country:Brazil
Document type:article
Access type:open access
Associated institution:IBICT
Language:English
Origin:Oasisbr
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author Maraschin,Thuany Garcia
author2 Correa,Roberto da Silva
Rodrigues,Luiz Frederico
Balzarettid,Naira Maria
Malmonge,José Antonio
Galland,Griselda Barrera
Basso,Nara Regina de Souza
author2_role author
author
author
author
author
author
author_facet Maraschin,Thuany Garcia
Correa,Roberto da Silva
Rodrigues,Luiz Frederico
Balzarettid,Naira Maria
Malmonge,José Antonio
Galland,Griselda Barrera
Basso,Nara Regina de Souza
author_role author
country_str BR
creators_json_txt [{\"Person.name\":\"Maraschin,Thuany Garcia\"},{\"Person.name\":\"Correa,Roberto da Silva\"},{\"Person.name\":\"Rodrigues,Luiz Frederico\"},{\"Person.name\":\"Balzarettid,Naira Maria\"},{\"Person.name\":\"Malmonge,José Antonio\"},{\"Person.name\":\"Galland,Griselda Barrera\"},{\"Person.name\":\"Basso,Nara Regina de Souza\"}]
datacite.creators.creator.creatorName.fl_str_mv Maraschin,Thuany Garcia
Correa,Roberto da Silva
Rodrigues,Luiz Frederico
Balzarettid,Naira Maria
Malmonge,José Antonio
Galland,Griselda Barrera
Basso,Nara Regina de Souza
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv Graphene oxide
reduced graphene oxide, chitosan
biodegradable polymer
datacite.titles.title.fl_str_mv Chitosan Nanocomposites with Graphene-Based Filler
dc.creator.none.fl_str_mv Maraschin,Thuany Garcia
Correa,Roberto da Silva
Rodrigues,Luiz Frederico
Balzarettid,Naira Maria
Malmonge,José Antonio
Galland,Griselda Barrera
Basso,Nara Regina de Souza
dc.format.none.fl_str_mv text/html
dc.identifier.none.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700288
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv ABM, ABC, ABPol
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.source.none.fl_str_mv Materials Research v.22 suppl.1 2019
reponame:Materials research (São Carlos. Online)
instname:Universidade Federal de São Carlos (UFSCAR)
instacron:ABM ABC ABPOL
dc.subject.none.fl_str_mv Graphene oxide
reduced graphene oxide, chitosan
biodegradable polymer
dc.title.fl_str_mv Chitosan Nanocomposites with Graphene-Based Filler
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description This study evaluates the properties of chitosan (CS) membranes modified with different percentages (0.5%, 3%, and 5% w/w) of a graphene-based material. Graphene oxide (GO) and reduced graphene oxide (RGO) were obtained by the chemical exfoliation of graphite and thermal reduction. Then, they were characterized by electrical conductivity measurements, FESEM, XRD, AFM, and Raman spectroscopy. The composites’ morphology was evaluated by FESEM. The degree of swelling over a 48 h period and mass loss behavior in phosphate-buffered saline solution for up to 70 days were also studied. The hydrophilicity of the CS and CS/graphene nanocomposites was examined by water contact angle. The graphene materials showed small stacks (6-8 sheets) with low defect density and nanoscale thickness (1.3-5.9 nm). The dispersion of the graphene material in the CS matrix significantly decreased the degree of swelling (460%) but did not modify the hydrolytic degradation process and the hydrophilicity of membranes.
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organization_str_mv urn:organizationAcronym:oasisbr
person_str_mv Maraschin,Thuany Garcia
Correa,Roberto da Silva
Rodrigues,Luiz Frederico
Balzarettid,Naira Maria
Malmonge,José Antonio
Galland,Griselda Barrera
Basso,Nara Regina de Souza
publishDate 2019
publisher.none.fl_str_mv ABM, ABC, ABPol
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spelling Chitosan Nanocomposites with Graphene-Based FillerMaraschin,Thuany GarciaCorrea,Roberto da SilvaRodrigues,Luiz FredericoBalzarettid,Naira MariaMalmonge,José AntonioGalland,Griselda BarreraBasso,Nara Regina de SouzaGraphene oxidereduced graphene oxide, chitosanbiodegradable polymeropen accesshttp://purl.org/coar/access_right/c_abf2http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700288URLhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700288URLHasVersion2019-01-01This study evaluates the properties of chitosan (CS) membranes modified with different percentages (0.5%, 3%, and 5% w/w) of a graphene-based material. Graphene oxide (GO) and reduced graphene oxide (RGO) were obtained by the chemical exfoliation of graphite and thermal reduction. Then, they were characterized by electrical conductivity measurements, FESEM, XRD, AFM, and Raman spectroscopy. The composites’ morphology was evaluated by FESEM. The degree of swelling over a 48 h period and mass loss behavior in phosphate-buffered saline solution for up to 70 days were also studied. The hydrophilicity of the CS and CS/graphene nanocomposites was examined by water contact angle. The graphene materials showed small stacks (6-8 sheets) with low defect density and nanoscale thickness (1.3-5.9 nm). The dispersion of the graphene material in the CS matrix significantly decreased the degree of swelling (460%) but did not modify the hydrolytic degradation process and the hydrophilicity of membranes.engtext/htmlABM, ABC, ABPolMaterials Research v.22 suppl.1 2019reponame:Materials research (São Carlos. Online)instname:Universidade Federal de São Carlos (UFSCAR)instacron:ABM ABC ABPOLjournal articlehttp://purl.org/coar/resource_type/c_6501literatureVoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85
spellingShingle Chitosan Nanocomposites with Graphene-Based Filler
Maraschin,Thuany Garcia
Graphene oxide
reduced graphene oxide, chitosan
biodegradable polymer
status SINGLETON
status_str VoR
subject.fl_str_mv Graphene oxide
reduced graphene oxide, chitosan
biodegradable polymer
title Chitosan Nanocomposites with Graphene-Based Filler
title_full Chitosan Nanocomposites with Graphene-Based Filler
title_fullStr Chitosan Nanocomposites with Graphene-Based Filler
title_full_unstemmed Chitosan Nanocomposites with Graphene-Based Filler
title_short Chitosan Nanocomposites with Graphene-Based Filler
title_sort Chitosan Nanocomposites with Graphene-Based Filler
topic Graphene oxide
reduced graphene oxide, chitosan
biodegradable polymer
topic_facet Graphene oxide
reduced graphene oxide, chitosan
biodegradable polymer
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000700288
visible 1

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