Publicação
A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib
| Resumo: | The demand for lithium-ion batteries (LIBs) is exponentially rising driven by the increasing variety of their applications, which includes consumer electronics, stationary energy storage, and especially electromobility. To meet this increasing demand, recycling becomes necessary since, in addition to reducing the environmental impact of the LIBs, it mitigates the challenges of scarcity of lithium (Li) and other valuable metals such as cobalt (Co), nickel (Ni), and manganese (Mn). In this paper, we propose and demonstrate a technology for recycling LIB cells that recovers active materials and other elements contained in LIB cells. The reported technology, which we denominated RecycLib, employs hydrometallurgy and can be applied to lithium cobalt oxide LiCoO2 (LCO) with cylindrical and prismatic geometries, as well as lithium nickel manganese cobalt oxide LiNixCoyMnzO2 (NMC) cells. Experimental characterization reveals recovery efficiency rates of the cathodic metallic oxide higher than 90 % for LCO (with 98 % purity in the case of cylindrical LIB cells and 80 % for prismatic cells) and 80 % for NMC LIB cells (with 85 % purity) employing relatively inexpensive reagents with low environmental hazardous potential and sub-processes designed according to Circular Economy precepts. Therefore, it is envisaged that the proposed technology to show a low potential for environmental impact, low operating costs, and high work safety, thus favoring industrial scalability. |
|---|---|
| Autores principais: | Santos, M.P. dos |
| Outros Autores: | Garde, Ivan Aritz Aldaya; Ronchini, Carolina Magda Bassoto; Filho, Lúcio Cardozo; Souza, Guilherme Botelho Meireles de; Abbade, Marcelo Luís Francisco; Regone, Natal Nerímio; Jegatheesan, Veeriah (Jega); Oliveira, José Augusto de |
| Assunto: | Circular economy Lithium-ion battery Recycling |
| Ano: | 2022 |
| País: | Brasil |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | IBICT |
| Idioma: | inglês |
| Origem: | Oasisbr |
| _version_ | 1871586296440291328 |
|---|---|
| author | Santos, M.P. dos |
| author2 | Garde, Ivan Aritz Aldaya Ronchini, Carolina Magda Bassoto Filho, Lúcio Cardozo Souza, Guilherme Botelho Meireles de Abbade, Marcelo Luís Francisco Regone, Natal Nerímio Jegatheesan, Veeriah (Jega) Oliveira, José Augusto de |
| author2_role | author author author author author author author author |
| author_facet | Santos, M.P. dos Garde, Ivan Aritz Aldaya Ronchini, Carolina Magda Bassoto Filho, Lúcio Cardozo Souza, Guilherme Botelho Meireles de Abbade, Marcelo Luís Francisco Regone, Natal Nerímio Jegatheesan, Veeriah (Jega) Oliveira, José Augusto de |
| author_role | author |
| country_str | BR |
| creators_json_txt | [{\"Person.name\":\"Santos, M.P. dos\"},{\"Person.name\":\"Garde, Ivan Aritz Aldaya\"},{\"Person.name\":\"Ronchini, Carolina Magda Bassoto\"},{\"Person.name\":\"Filho, Lúcio Cardozo\"},{\"Person.name\":\"Souza, Guilherme Botelho Meireles de\"},{\"Person.name\":\"Abbade, Marcelo Luís Francisco\"},{\"Person.name\":\"Regone, Natal Nerímio\"},{\"Person.name\":\"Jegatheesan, Veeriah (Jega)\"},{\"Person.name\":\"Oliveira, José Augusto de\"}] |
| datacite.creators.creator.creatorName.fl_str_mv | Santos, M.P. dos Garde, Ivan Aritz Aldaya Ronchini, Carolina Magda Bassoto Filho, Lúcio Cardozo Souza, Guilherme Botelho Meireles de Abbade, Marcelo Luís Francisco Regone, Natal Nerímio Jegatheesan, Veeriah (Jega) Oliveira, José Augusto de |
| datacite.date.Accepted.fl_str_mv | 2021-12-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2022-04-28T19:44:15Z |
| datacite.date.embargoed.fl_str_mv | 2022-04-28T19:44:15Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | Circular economy Lithium-ion battery Recycling |
| datacite.titles.title.fl_str_mv | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| dc.creator.none.fl_str_mv | Santos, M.P. dos Garde, Ivan Aritz Aldaya Ronchini, Carolina Magda Bassoto Filho, Lúcio Cardozo Souza, Guilherme Botelho Meireles de Abbade, Marcelo Luís Francisco Regone, Natal Nerímio Jegatheesan, Veeriah (Jega) Oliveira, José Augusto de |
| dc.date.Accepted.fl_str_mv | 2021-12-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2022-04-28T19:44:15Z |
| dc.date.embargoed.fl_str_mv | 2022-04-28T19:44:15Z |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/11449/222365 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.source.none.fl_str_mv | reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
| dc.subject.none.fl_str_mv | Circular economy Lithium-ion battery Recycling |
| dc.title.fl_str_mv | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | The demand for lithium-ion batteries (LIBs) is exponentially rising driven by the increasing variety of their applications, which includes consumer electronics, stationary energy storage, and especially electromobility. To meet this increasing demand, recycling becomes necessary since, in addition to reducing the environmental impact of the LIBs, it mitigates the challenges of scarcity of lithium (Li) and other valuable metals such as cobalt (Co), nickel (Ni), and manganese (Mn). In this paper, we propose and demonstrate a technology for recycling LIB cells that recovers active materials and other elements contained in LIB cells. The reported technology, which we denominated RecycLib, employs hydrometallurgy and can be applied to lithium cobalt oxide LiCoO2 (LCO) with cylindrical and prismatic geometries, as well as lithium nickel manganese cobalt oxide LiNixCoyMnzO2 (NMC) cells. Experimental characterization reveals recovery efficiency rates of the cathodic metallic oxide higher than 90 % for LCO (with 98 % purity in the case of cylindrical LIB cells and 80 % for prismatic cells) and 80 % for NMC LIB cells (with 85 % purity) employing relatively inexpensive reagents with low environmental hazardous potential and sub-processes designed according to Circular Economy precepts. Therefore, it is envisaged that the proposed technology to show a low potential for environmental impact, low operating costs, and high work safety, thus favoring industrial scalability. |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| id | oasisbr_7851385e4b9cd7e50de38da5bb2fef79 |
| identifier.url.fl_str_mv | http://hdl.handle.net/11449/222365 |
| inst_facet_str | urn:organizationAcronym:oasisbr{{{_:::_}}}IBICT |
| instacron_str | OASISBR |
| institution | IBICT |
| instname_str | IBICT |
| language | eng |
| network_acronym_str | oasisbr |
| network_name_str | Oasisbr |
| oai_identifier_str | oai:repositorio.unesp.br:11449/222365 |
| organization_str_mv | urn:organizationAcronym:oasisbr |
| person_str_mv | Santos, M.P. dos Garde, Ivan Aritz Aldaya Ronchini, Carolina Magda Bassoto Filho, Lúcio Cardozo Souza, Guilherme Botelho Meireles de Abbade, Marcelo Luís Francisco Regone, Natal Nerímio Jegatheesan, Veeriah (Jega) Oliveira, José Augusto de |
| publishDate | 2022 |
| repo_facet_str | urn:repositoryAcronym:oasisbr{{{_:::_}}}Oasisbr |
| reponame_str | Oasisbr |
| repository_id_str | urn:repositoryAcronym:oasisbr |
| service_str_mv | urn:repositoryAcronym:oasisbr |
| spelling | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLibSantos, M.P. dosGarde, Ivan Aritz AldayaRonchini, Carolina Magda BassotoFilho, Lúcio CardozoSouza, Guilherme Botelho Meireles deAbbade, Marcelo Luís FranciscoRegone, Natal NerímioJegatheesan, Veeriah (Jega)Oliveira, José Augusto deCircular economyLithium-ion batteryRecyclingopen accesshttp://purl.org/coar/access_right/c_abf2http://hdl.handle.net/11449/222365HandleResources, Conservation and Recycling, v. 175.N/AHasVersion1879-0658N/AHasVersion0921-3449N/AHasVersion2-s2.0-85114375174N/AHasVersionhttps://doi.org/http://dx.doi.org/10.1016/j.resconrec.2021.105863DOIhttp://hdl.handle.net/11449/222365Handlehttps://doi.org/10.1016/j.resconrec.2021.105863DOI2022-04-28T19:44:15Z2022-04-282021-12-01T00:00:00ZThe demand for lithium-ion batteries (LIBs) is exponentially rising driven by the increasing variety of their applications, which includes consumer electronics, stationary energy storage, and especially electromobility. To meet this increasing demand, recycling becomes necessary since, in addition to reducing the environmental impact of the LIBs, it mitigates the challenges of scarcity of lithium (Li) and other valuable metals such as cobalt (Co), nickel (Ni), and manganese (Mn). In this paper, we propose and demonstrate a technology for recycling LIB cells that recovers active materials and other elements contained in LIB cells. The reported technology, which we denominated RecycLib, employs hydrometallurgy and can be applied to lithium cobalt oxide LiCoO2 (LCO) with cylindrical and prismatic geometries, as well as lithium nickel manganese cobalt oxide LiNixCoyMnzO2 (NMC) cells. Experimental characterization reveals recovery efficiency rates of the cathodic metallic oxide higher than 90 % for LCO (with 98 % purity in the case of cylindrical LIB cells and 80 % for prismatic cells) and 80 % for NMC LIB cells (with 85 % purity) employing relatively inexpensive reagents with low environmental hazardous potential and sub-processes designed according to Circular Economy precepts. Therefore, it is envisaged that the proposed technology to show a low potential for environmental impact, low operating costs, and high work safety, thus favoring industrial scalability.engreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPjournal articlehttp://purl.org/coar/resource_type/c_6501literatureVoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85 |
| spellingShingle | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib Santos, M.P. dos Circular economy Lithium-ion battery Recycling |
| status | SINGLETON |
| status_str | VoR |
| subject.fl_str_mv | Circular economy Lithium-ion battery Recycling |
| title | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| title_full | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| title_fullStr | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| title_full_unstemmed | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| title_short | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| title_sort | A technology for recycling lithium-ion batteries promoting the circular economy: The RecycLib |
| topic | Circular economy Lithium-ion battery Recycling |
| topic_facet | Circular economy Lithium-ion battery Recycling |
| url | http://hdl.handle.net/11449/222365 |
| visible | 1 |
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