Publicação
Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme
| Resumo: | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) |
|---|---|
| Autores principais: | Baldo, Thaísa A. |
| Outros Autores: | David-Parra, Diego N.; Gomes, Homero M.; Seraphim, Patrícia M.; Teixeira, Marcos F.S. |
| Assunto: | Electrocatalysis Self-assembled monolayer Sensorial platform Tafel-Marcus |
| Ano: | 2018 |
| País: | Brasil |
| Tipo de documento: | artigo |
| Tipo de acesso: | acesso aberto |
| Instituição associada: | IBICT |
| Idioma: | inglês |
| Origem: | Oasisbr |
| _version_ | 1871568602637795328 |
|---|---|
| author | Baldo, Thaísa A. |
| author2 | David-Parra, Diego N. Gomes, Homero M. Seraphim, Patrícia M. Teixeira, Marcos F.S. |
| author2_role | author author author author |
| author_facet | Baldo, Thaísa A. David-Parra, Diego N. Gomes, Homero M. Seraphim, Patrícia M. Teixeira, Marcos F.S. |
| author_role | author |
| country_str | BR |
| creators_json_txt | [{\"Person.name\":\"Baldo, Thaísa A.\"},{\"Person.name\":\"David-Parra, Diego N.\"},{\"Person.name\":\"Gomes, Homero M.\"},{\"Person.name\":\"Seraphim, Patrícia M.\"},{\"Person.name\":\"Teixeira, Marcos F.S.\"}] |
| datacite.creators.creator.creatorName.fl_str_mv | Baldo, Thaísa A. David-Parra, Diego N. Gomes, Homero M. Seraphim, Patrícia M. Teixeira, Marcos F.S. |
| datacite.date.Accepted.fl_str_mv | 2018-04-01T00:00:00Z |
| datacite.date.available.fl_str_mv | 2018-12-11T16:52:14Z |
| datacite.date.embargoed.fl_str_mv | 2018-12-11T16:52:14Z |
| datacite.rights.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| datacite.subjects.subject.fl_str_mv | Electrocatalysis Self-assembled monolayer Sensorial platform Tafel-Marcus |
| datacite.titles.title.fl_str_mv | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| dc.creator.none.fl_str_mv | Baldo, Thaísa A. David-Parra, Diego N. Gomes, Homero M. Seraphim, Patrícia M. Teixeira, Marcos F.S. |
| dc.date.Accepted.fl_str_mv | 2018-04-01T00:00:00Z |
| dc.date.available.fl_str_mv | 2018-12-11T16:52:14Z |
| dc.date.embargoed.fl_str_mv | 2018-12-11T16:52:14Z |
| dc.description.none.fl_str_mv | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Processo FAPESP: 2012/21703-7 CNPq: 234256/2014-1 CNPq: 302728/2012-0 In this study, we explore the fabrication and properties of a sensing electrochemical platform that is based on a novel 11-mercaptoundecyl-N′,N″,N‴-trimethylammonium hexacyanoferrate (MAH) and 6-(ferrocenyl)hexanethiol (FT)/glucose oxidase (GOx) on gold substrate. The hexacyanoferrate and ferrocene moieties that were immobilized on the gold surface were examined as electron transfer mediators with the oxidase glucose. The sensing platform, based on 11-mercaptoundecyl-N′,N″,N‴-trimethylammonium hexacyanoferrate (MAH) and 6-(ferrocenyl)hexanethiol (FT)/GOx modified gold electrode, shows the potential to work with two distinct mechanisms for electrochemical response. The hexacyanoferrate anion that was anchored at positive edge charge of the 11-mercaptoundecyl-N′,N″,N‴-trimethylammonium on the gold surface provided an efficient electron transfer. It was demonstrated that in the design of the GOx/MAH, the FT/Au electrode is facilitating the electron transfer from GOx toward the gold substrate. We believe that this study adds a new facet to nanobioelectronics with applications for biofuels and sensorial platforms. |
| dc.format.none.fl_str_mv | 37-44 |
| dc.identifier.none.fl_str_mv | http://hdl.handle.net/11449/170741 |
| dc.language.none.fl_str_mv | eng |
| dc.rights.none.fl_str_mv | http://purl.org/coar/access_right/c_abf2 |
| dc.source.none.fl_str_mv | reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
| dc.subject.none.fl_str_mv | Electrocatalysis Self-assembled monolayer Sensorial platform Tafel-Marcus |
| dc.title.fl_str_mv | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| dc.type.none.fl_str_mv | http://purl.org/coar/resource_type/c_6501 |
| description | Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) |
| dirty | 0 |
| eu_rights_str_mv | openAccess |
| format | article |
| id | oasisbr_3e025fd9bee654bbfb6fef05cc2d1fac |
| identifier.url.fl_str_mv | http://hdl.handle.net/11449/170741 |
| inst_facet_str | urn:organizationAcronym:oasisbr{{{_:::_}}}IBICT |
| instacron_str | OASISBR |
| institution | IBICT |
| instname_str | IBICT |
| language | eng |
| network_acronym_str | oasisbr |
| network_name_str | Oasisbr |
| oai_identifier_str | oai:repositorio.unesp.br:11449/170741 |
| organization_str_mv | urn:organizationAcronym:oasisbr |
| person_str_mv | Baldo, Thaísa A. David-Parra, Diego N. Gomes, Homero M. Seraphim, Patrícia M. Teixeira, Marcos F.S. |
| publishDate | 2018 |
| repo_facet_str | urn:repositoryAcronym:oasisbr{{{_:::_}}}Oasisbr |
| reponame_str | Oasisbr |
| repository_id_str | urn:repositoryAcronym:oasisbr |
| service_str_mv | urn:repositoryAcronym:oasisbr |
| spelling | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzymeBaldo, Thaísa A.David-Parra, Diego N.Gomes, Homero M.Seraphim, Patrícia M.Teixeira, Marcos F.S.ElectrocatalysisSelf-assembled monolayerSensorial platformTafel-Marcusopen accesshttp://purl.org/coar/access_right/c_abf2http://hdl.handle.net/11449/170741HandleSensing and Bio-Sensing Research, v. 18, p. 37-44.N/AHasVersion2214-1804N/AHasVersion2-s2.0-85042936224N/AHasVersion2-s2.0-85042936224.pdfN/AHasVersion0411008599070871N/AHasVersion0000-0003-2145-6640N/AHasVersionhttps://doi.org/http://dx.doi.org/10.1016/j.sbsr.2018.02.007DOIhttp://hdl.handle.net/11449/170741Handlehttps://doi.org/10.1016/j.sbsr.2018.02.007DOI2018-12-11T16:52:14Z2018-12-112018-04-01T00:00:00ZFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Processo FAPESP: 2012/21703-7CNPq: 234256/2014-1CNPq: 302728/2012-0In this study, we explore the fabrication and properties of a sensing electrochemical platform that is based on a novel 11-mercaptoundecyl-N′,N″,N‴-trimethylammonium hexacyanoferrate (MAH) and 6-(ferrocenyl)hexanethiol (FT)/glucose oxidase (GOx) on gold substrate. The hexacyanoferrate and ferrocene moieties that were immobilized on the gold surface were examined as electron transfer mediators with the oxidase glucose. The sensing platform, based on 11-mercaptoundecyl-N′,N″,N‴-trimethylammonium hexacyanoferrate (MAH) and 6-(ferrocenyl)hexanethiol (FT)/GOx modified gold electrode, shows the potential to work with two distinct mechanisms for electrochemical response. The hexacyanoferrate anion that was anchored at positive edge charge of the 11-mercaptoundecyl-N′,N″,N‴-trimethylammonium on the gold surface provided an efficient electron transfer. It was demonstrated that in the design of the GOx/MAH, the FT/Au electrode is facilitating the electron transfer from GOx toward the gold substrate. We believe that this study adds a new facet to nanobioelectronics with applications for biofuels and sensorial platforms.eng37-44reponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPjournal articlehttp://purl.org/coar/resource_type/c_6501literatureVoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85 |
| spellingShingle | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme Baldo, Thaísa A. Electrocatalysis Self-assembled monolayer Sensorial platform Tafel-Marcus |
| status | SINGLETON |
| status_str | VoR |
| subject.fl_str_mv | Electrocatalysis Self-assembled monolayer Sensorial platform Tafel-Marcus |
| title | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| title_full | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| title_fullStr | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| title_full_unstemmed | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| title_short | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| title_sort | Study of binary self-assembled monolayers of a novel anchoring thiol (11-mercaptoundecyl-N′,N″,N‴-trimethylammonium) in the electron transfer with glucose oxidase enzyme |
| topic | Electrocatalysis Self-assembled monolayer Sensorial platform Tafel-Marcus |
| topic_facet | Electrocatalysis Self-assembled monolayer Sensorial platform Tafel-Marcus |
| url | http://hdl.handle.net/11449/170741 |
| visible | 1 |
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