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Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight

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Resumo:Here, we present the development and performance of a nanocomposite photocatalyst based on titanium dioxide (TiO2) and reduced graphene oxide (rGO). The material was prepared using a direct sol-gel method, followed by hydrothermal treatment. Different experimental conditions, such as time and temperature during the synthesis, were investigated with the aim to optimize photocatalytic degradation. The influence of the preparation conditions on the physicochemical properties of the synthesized powders was established by different characterization methods such as Scanning Electron Microscopy (SEM), and Raman spectroscopy. The effectiveness of the synthesized photocatalysts was examined through the photodegradation of caffeine under simulated sunlight irradiation. The influence of synthesized parameters on the TiO2/rGO performance for the photodegradation of pharmaceutical caffeine was monitored by UV-Vis spectroscopy. The obtained results show that the photocatalytic properties of the prepared TiO2/rGO composites depend on different experimental parameters of their synthesis procedure, such as time and temperature. The TiO2/rGO_6/400 composite presents a very efficient photo-degradation of caffeine by simulated sunlight irradiation, resulting in an efficiency of 95% within 90 minutes.
Autores principais:Kocijan, Martina
Outros Autores:Curkovic, Lidija; Radosevic, Tina; Podlogar, Matejka
Assunto:graphene oxide photocatalysis reduced graphene oxide TiO2/rGO composites visible irradiation
Ano:2020
País:Portugal
Tipo de documento:artigo
Tipo de acesso:unknown
Instituição associada:Universidade de Aveiro
Idioma:inglês
Origem:Nanomaterials Science & Engineering
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author Kocijan, Martina
author2 Curkovic, Lidija
Radosevic, Tina
Podlogar, Matejka
author2_role author
author
author
author_facet Kocijan, Martina
Curkovic, Lidija
Radosevic, Tina
Podlogar, Matejka
author_role author
country_str PT
creators_json_txt [{\"Person.name\":\"Kocijan, Martina\"},{\"Person.name\":\"Curkovic, Lidija\"},{\"Person.name\":\"Radosevic, Tina\"},{\"Person.name\":\"Podlogar, Matejka\"}]
datacite.creators.creator.creatorName.fl_str_mv Kocijan, Martina
Curkovic, Lidija
Radosevic, Tina
Podlogar, Matejka
datacite.rights.fl_str_mv http://purl.org/coar/access_right/c_abf2
datacite.subjects.subject.fl_str_mv graphene oxide
photocatalysis
reduced graphene oxide
TiO2/rGO composites
visible irradiation
datacite.titles.title.fl_str_mv Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
dc.creator.none.fl_str_mv Kocijan, Martina
Curkovic, Lidija
Radosevic, Tina
Podlogar, Matejka
dc.format.none.fl_str_mv application/pdf
dc.identifier.none.fl_str_mv https://doi.org/10.34624/nmse.v2i4.21063
dc.language.none.fl_str_mv eng
dc.publisher.none.fl_str_mv UA Editora
dc.rights.none.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.source.none.fl_str_mv Nanomaterials Science & Engineering; Vol. 2 No. 4 (2020): Nanomaterials Science & Engineering; 162-169
Journal of Nanomaterials Science and Nanotechnology; Vol. 2 Núm. 4 (2020): Nanomaterials Science & Engineering; 162-169
Journal of Nanomaterials Science and Nanotechnology; Vol. 2 No 4 (2020): Nanomaterials Science & Engineering; 162-169
Nanomaterials Science & Engineering; Vol. 2 N.º 4 (2020): Nanomaterials Science & Engineering; 162-169
2184-7002
2184-7002
dc.subject.none.fl_str_mv graphene oxide
photocatalysis
reduced graphene oxide
TiO2/rGO composites
visible irradiation
dc.title.fl_str_mv Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
dc.type.none.fl_str_mv http://purl.org/coar/resource_type/c_6501
description Here, we present the development and performance of a nanocomposite photocatalyst based on titanium dioxide (TiO2) and reduced graphene oxide (rGO). The material was prepared using a direct sol-gel method, followed by hydrothermal treatment. Different experimental conditions, such as time and temperature during the synthesis, were investigated with the aim to optimize photocatalytic degradation. The influence of the preparation conditions on the physicochemical properties of the synthesized powders was established by different characterization methods such as Scanning Electron Microscopy (SEM), and Raman spectroscopy. The effectiveness of the synthesized photocatalysts was examined through the photodegradation of caffeine under simulated sunlight irradiation. The influence of synthesized parameters on the TiO2/rGO performance for the photodegradation of pharmaceutical caffeine was monitored by UV-Vis spectroscopy. The obtained results show that the photocatalytic properties of the prepared TiO2/rGO composites depend on different experimental parameters of their synthesis procedure, such as time and temperature. The TiO2/rGO_6/400 composite presents a very efficient photo-degradation of caffeine by simulated sunlight irradiation, resulting in an efficiency of 95% within 90 minutes.
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identifier.doi.fl_str_mv https://doi.org/10.34624/nmse.v2i4.21063
inst_facet_str urn:organizationAcronym:ua{{{_:::_}}}Universidade de Aveiro
instacron_str ua
institution Universidade de Aveiro
instname_str Universidade de Aveiro
language eng
network_acronym_str nmse
network_name_str Nanomaterials Science & Engineering
oai_identifier_str oai:proa.ua.pt:article/21063
organization_str_mv urn:organizationAcronym:ua
person_str_mv Kocijan, Martina
Curkovic, Lidija
Radosevic, Tina
Podlogar, Matejka
publishDate 2020
publisher.none.fl_str_mv UA Editora
repo_facet_str urn:repositoryAcronym:nmse{{{_:::_}}}Nanomaterials Science & Engineering
reponame_str Nanomaterials Science & Engineering
repository_id_str urn:repositoryAcronym:nmse
service_str_mv urn:repositoryAcronym:nmse
spelling enPhotocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlightKocijan, MartinaCurkovic, LidijaRadosevic, TinaPodlogar, Matejkagraphene oxidephotocatalysisreduced graphene oxideTiO2/rGO compositesvisible irradiationCopyright (c) 2020 Nanomaterials Science & Engineeringhttp://purl.org/coar/access_right/c_abf2https://doi.org/10.34624/nmse.v2i4.21063DOIhttps://proa.ua.pt/index.php/nmse/article/view/21063URLHasVersionhttps://proa.ua.pt/index.php/nmse/article/view/21063/16882URLHasVersionhttps://doi.org/10.34624/nmse.v2i4.21063DOI2020-12-11enHere, we present the development and performance of a nanocomposite photocatalyst based on titanium dioxide (TiO2) and reduced graphene oxide (rGO). The material was prepared using a direct sol-gel method, followed by hydrothermal treatment. Different experimental conditions, such as time and temperature during the synthesis, were investigated with the aim to optimize photocatalytic degradation. The influence of the preparation conditions on the physicochemical properties of the synthesized powders was established by different characterization methods such as Scanning Electron Microscopy (SEM), and Raman spectroscopy. The effectiveness of the synthesized photocatalysts was examined through the photodegradation of caffeine under simulated sunlight irradiation. The influence of synthesized parameters on the TiO2/rGO performance for the photodegradation of pharmaceutical caffeine was monitored by UV-Vis spectroscopy. The obtained results show that the photocatalytic properties of the prepared TiO2/rGO composites depend on different experimental parameters of their synthesis procedure, such as time and temperature. The TiO2/rGO_6/400 composite presents a very efficient photo-degradation of caffeine by simulated sunlight irradiation, resulting in an efficiency of 95% within 90 minutes.UA Editoraapplication/pdfenNanomaterials Science & Engineering; Vol. 2 No. 4 (2020): Nanomaterials Science & Engineering; 162-169esJournal of Nanomaterials Science and Nanotechnology; Vol. 2 Núm. 4 (2020): Nanomaterials Science & Engineering; 162-169frJournal of Nanomaterials Science and Nanotechnology; Vol. 2 No 4 (2020): Nanomaterials Science & Engineering; 162-169ptNanomaterials Science & Engineering; Vol. 2 N.º 4 (2020): Nanomaterials Science & Engineering; 162-1692184-70022184-7002engjournal articlehttp://purl.org/coar/resource_type/c_6501literatureVoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85
spellingShingle Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
Kocijan, Martina
graphene oxide
photocatalysis
reduced graphene oxide
TiO2/rGO composites
visible irradiation
status SINGLETON
status_str VoR
subject.fl_str_mv graphene oxide
photocatalysis
reduced graphene oxide
TiO2/rGO composites
visible irradiation
title Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
title_full Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
title_fullStr Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
title_full_unstemmed Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
title_short Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
title_sort Photocatalytic degradation of organic pollutant using TiO2/rGO nanocomposites under simulated sunlight
topic graphene oxide
photocatalysis
reduced graphene oxide
TiO2/rGO composites
visible irradiation
topic_facet graphene oxide
photocatalysis
reduced graphene oxide
TiO2/rGO composites
visible irradiation
url https://doi.org/10.34624/nmse.v2i4.21063
visible 1

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