Ice accretion is a common issue on aircraft flying in cold climate conditions. The ice accumulation on aircraft surfaces disturbs the adjacent airflow field, increases the drag, and significantly reduces the aircraft’s aerodynamic performance. It also increases the weight of the aircraft and causes the failure of critical components in some situations, leading to premature aerodynamic stall and loss of control and lift. With this in mind, several authors have begun to study the thermal effects of plasma actuators for icing control and mitigation, considering both aeronautical and wind energy applications. Although this is a recent topic, several studies have already been performed, and it is clear this topic has attracted the attention of several research groups. Considering the importance and potential of using dielectric barrier discharge (DBD) plasma actuators for ice mitigation, we aim to present in this paper the first review on this topic, summarizing all the information reported in the literature about three major subtopics: thermal effects induced by DBD plasma actuators, plasma actuators’ ability in deicing and ice formation prevention, and ice detection capability of DBD plasma actuators. An overview of the characteristics of these devices is performed and conclusions are drawn regarding recent developments in the application of plasma actuators for icing mitigation purposes.

Energy harvesting from the environment based on electroactive polymers has been increasing in recent years. Ferroelectric polymers are used as mechanical-to-electrical energy transducers in a wide range of applications, scavenging the surrounding energy to power low-power devices. These energy-harvesting systems operate by taking advantage of the piezoelectric, pyroelectric, and magnetoelectric properties of the polymers, harvesting wasted environmental energy and converting it mainly into electrical energy. There have been developed different nano- and micro-scale power harvesters with an increasing interest for powering mobile electronics and low-power devices, including applications in remote access areas. Novel electronic devices are developed based on low-power solutions, and therefore, polymer-based materials represent a suitable solution to power these devices. Among the different polymers, the most widely used in the device application is the poly(vinylidene fluoride) (PVDF) family, due to its higher output performance.

Dielectric Barrier Discharge (DBD) plasma actuators are simple devices with great potential for active flow control applications. Further, it has been recently proven their ability for applications in the area of heat transfer, such as film cooling of turbine blades or ice removal. The dielectric material used in the fabrication of these devices is essential in determining the device performance. However, the variety of dielectric materials studied in the literature is very limited and the majority of the authors only use Kapton, Teflon, Macor ceramic or poly(methyl methacrylate) (PMMA). Furthermore, several authors reported difficulties in the durability of the dielectric layer when the actuators operate at high voltage and frequency. Also, it has been reported that, after long operation time, the dielectric layer suffers degradation due to its exposure to plasma discharge, degradation that may lead to the failure of the device. Considering the need of durable and robust actuators, as well as the need of higher flow control efficiencies, it is highly important to develop new dielectric materials which may be used for plasma actuator fabrication. In this context, the present study reports on the experimental testing of dielectric materials which can be used for DBD plasma actuators fabrication. Plasma actuators fabricated of poly(vinylidene fluoride) (PVDF) and polystyrene (PS) have been fabricated and evaluated. Although these dielectric materials are not commonly used as dielectric layer of plasma actuators, their interesting electrical and dielectric properties and the possibility of being used as sensors, indicate their suitability as potential alternatives to the standard used materials. The plasma actuators produced with these nonstandard dielectric materials were analyzed in terms of electrical characteristics, generated flow velocity and mechanical efficiency, and the obtained results were compared with a standard actuator made of Kapton. An innovative calorimetric method was implemented in order to estimate the thermal power transferred by these devices to an adjacent flow. These results allowed to discuss the ability of these new dielectric materials not only for flow control applications but also for heat transfer applications.

The massive use of fibre reinforced plastics (FRP) in several industrial sectors such as aeronautics, aerospace, or wind turbines, raises serious environmental concerns with respect to the end-of-life of these structures, based on their poor recyclability. The low density of FRP gives it outstanding specific properties, such as strength and stiffness, when compared to materials with high recyclability rates, such as metals1. FRP find several applications in structures in which the aerodynamic performance is of extreme importance to guarantee a proper operation. In this sense, to endow these structures with the ability to control or modulate the flow around their surface could be an extraordinary feature to improve the performance of the structure, thus saving considerable amounts of energy and increasing its useful life cycle, contributing in this sense also to reduce the environmental impact of the materials. This work is focused on the development of dielectric barrier discharge (DBD) plasma actuators supported on fibre reinforced thermosetting composites, which can be used in manufacturing of wind turbine blades: epoxy resin and glass, aramid (Fig. 1) and natural flax fibres. DBD plasma actuators are electrohydrodynamic devices capable of generating induced flows of a few m/s through nonthermal plasma, that can be successfully leveraged for flow control applications2, 3. The characterization of the system was carried out in terms of mechanical (flexural strength, strain and stiffness), electrical (power consumption, capacitance, charge-discharge cycles) and electromechanical (induced flow velocity, electromechanical power and efficiency) properties. The results showed the multifunctionality of the composites, demonstrating their suitability for the application, in particular, the epoxy/glass composite with a bending stress of ≈600 MPa, which obtained an induced flow velocity of ≈2.1 m/s with a power consumption of ≈15.1 W, when powered by an AC signal of 11 kVpp and 24 kHz.

The developed research presents a novel experimental study of the cost-effective MgO-Al2O3, MgO-CaZrO3 perovskite, and thermally stable YSZ ceramic composites for DBD plasma actuators in aerospace applications. This study focuses on the implementation of ceramic DBD plasma actuators for aerodynamic flow control and ice creation mitigation. For this purpose, electrical power consumption analysis, induced flow velocities assessment, and mechanical and thermal characterization were performed. MgO-Al2O3 presented higher induced velocities than its zirconia-based counterparts of up to 3.3 m/s, and lower heat dissipation, achieving a ceiling temperature of 46 ºC, being thereby the best-suited candidate for active flow control mechanisms. In contrast, YSZ had very high-power consumption translated into a maximum surface temperature of 155.4 ºC, establishing itself for ice mitigation. This extensive research evinces that the strategic combination of the developed ceramics’ thermomechanical, thermoelectric, and electromechanical properties allows them to be a promising breakthrough material for DBD plasma actuators.

In the areas of aeronautics and aerospace, ceramic composites play an essential and increasing role due to their superior performance and tailorable properties, exhibiting highly specialized mechanical, thermal, and electric features1. Their main applications include thermal protection systems (TPS), thermal barrier coatings (TBC), and dielectric barrier discharge (DBD) plasma actuators, both for instrumentation and control purposes2. This work reports the manufacture and characterization of three ceramic composites capable of fulfilling the multifunctional ceramic condition according to the aforementioned applications. Accordingly, MgO-Al2O3 (MA), MgOCaZrO3 (MCZ), and Y2O3 stabilized ZrO2 (YSZ) are introduced for TPS, TBC, and DBD dielectric elements. To this aim, MA, MCZ, and YSZ ceramic composites were fabricated via a sequential process, encompassing the selection of raw powders and milling, die pressing, and sintering. Further, the samples were polished for surface optimization. Overall, the results obtained, including mechanical (Young’s and shear moduli, flexural strength, hardness, and fracture toughness), thermal (thermal conductivity and thermal expansion (CTE)), and electrical (dielectric constant) properties, report evidence that the developed ceramics show suitable multifunctional characteristics and therefore fulfil the aeronautical and aerospace demands for increased materials performances. The combined analysis of the Young’s and shear moduli (Fig.1a) with the CTE – the latter over a wide range of temperatures (Fig. 1b) – allows concluding that the cost-effective and widely used alumina appears suitable for bulk monolithic (TPS) and joint applications (TPS, TBC, and DBD).

Three composite materials with different CaZrO3/MgO fractions (2/3, 1/2, 1/3) and two single-phase materials (CaZrO3 and MgO) were fabricated and their thermal conductivity was investigated. Complete thermal and mechanical characterizations (thermal expansion coefficient, thermal diffusivity, specific heat, hardness and toughness) of the materials were performed. Values of the thermal conductivity up to 480 ◦C of the composites were compared with those calculated with the main analytical models. From the real microstructures of the three composites, representative volume elements (RVE) were built and used for finite element modelling (FEM) of thermal conductivity using conductivities of the single-phase materials as inputs. The FEM results showed no differences for the 3 spatial directions of the RVE, nor for the different edge lengths (11, 14 and 17 μm). Results of all analytical models are statistically different from the experimental ones, being those from the Bruggeman model the closest. Results of the proposed FEM are statistically coincident with the experimental ones, showing sensitivity to temperature variation.

Starting from synthetic raw materials (CaZrO3 and MgO), microstructural and mechanical properties were optimised in order to obtain dense multiphasic ceramic, then finite element method (FEM) of an equimolar (1:1) CaZrO3-MgO composite was performed in order to obtain the effective elastic modulus. Composite presents two main phases of orthorhombic CaZrO3 (81.5 wt.%) and cubic MgO (18.5 wt.%); For 1500 °C, relative density of 99.9%, characteristic strength of 168 MPa, hardness of 7.8 MPa and toughness of 2.5 MPa.m1/2 were obtained. FEM simulation was performed using two representative volume elements (RVE’s) with edge lengths of 14 μm (933 grains) and 17 μm (1670 grains), using isotropic elastic model, and anisotropic on specific set of crystallographic planes. The results of FEM using isotropic approach for the two RVE’s are perfectly aligned with the experimental (245 GPa), while the anisotropic model shows a difference of 6.5%.

The quest for increased performance in the aeronautical and aerospace industries has provided the driving force and motivation for the research, investigation, and development of advanced ceramics. Special emphasis is therefore attributed to the ability of fine ceramics to fulfill an attractive, extreme, and distinguishing combination of application requirements. This is impelled by ensuring a suitable arrangement of thermomechanical, thermoelectric, and electromechanical properties. As a result, the reliability, durability, and useful lifetime extension of a critical structure or system are expected. In this context, engineered ceramic appliances consist of three main purposes in aeronautical and aerospace fields: thermal protection systems (TPS), thermal protection barriers (TBC), and dielectric barrier discharge (DBD) plasma actuators. Consequently, this research provides an extensive discussion and review of the referred applications, i.e., TPS, TBC, and DBD, and discusses the concept of multifunctional advanced ceramics for future engineering needs and perspectives.

This manuscript reports on the modification of the surface wettability of poly (vinylidene fluoride) (PVDF) and PVDF copolymer films and membranes by plasma treatments at different conditions, under oxygen and argon atmospheres. It is shown that a more pronounced decrease of the contact angle after O2 plasma treatments is obtained, with a decrease of ∼20-30° for PVDF and its copolymers films, leading also to superhydrophilic membranes. This effect is related to a defluorination process, followed by the incorporation of oxygen atoms onto the surface of membranes that occurs during the surface modification. The influence of plasma treatments on surface morphology and topography was studied by atomic force microscopy, showing a decrease in the mean surface roughness with the plasma treatments, being more noticeable for Ar treatments. Finally, it is also shown that plasma treatments under Ar and O2 did not induce modifications in the physicochemical and thermal properties of PVDF and PVDF copolymers. The chemical reaction mechanism after plasma treatment is proposed for the different copolymers.